Complex transition metal hydrides: Linear correlation of countercation electronegativity versus T-D bond lengths

Humphries, Terry; Sheppard, Drew; Buckley, Craig

doi:http://doi.org/10.1039/c5cc03654b

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Authors

Humphries, Terry

Sheppard, Drew

Buckley, Craig

Date

2015

Type

Journal Article

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Abstract

© 2015 The Royal Society of Chemistry. For homoleptic 18-electron complex hydrides, an inverse linear correlation has been established between the T-deuterium bond length (T = Fe, Co, Ni) and the average electronegativity of the metal countercations. This relationship can be further employed towards aiding structural solutions and predicting physical properties of novel complex transition metal hydrides.

Citation

Humphries, T. and Sheppard, D. and Buckley, C. 2015. Complex transition metal hydrides: Linear correlation of countercation electronegativity versus T-D bond lengths. Chemical Communications. 51 (56): pp. 11248-11251.

Source Title

Chemical Communications

URI

http://hdl.handle.net/20.500.11937/4697

DOI

http://doi.org/10.1039/c5cc03654b

Department

Department of Physics and Astronomy

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Research Papers