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dc.contributor.authorSzilagyi, Petra
dc.contributor.authorLutz, M.
dc.contributor.authorGascon, J.
dc.contributor.authorJuan-Alcaniz, J.
dc.contributor.authorEsch, J.
dc.contributor.authorKapteijn, F.
dc.contributor.authorGeerlings, H.
dc.contributor.authorDam, B.
dc.contributor.authorKrol, R.
dc.date.accessioned2017-03-15T22:02:38Z
dc.date.available2017-03-15T22:02:38Z
dc.date.created2017-02-24T00:09:24Z
dc.date.issued2013
dc.identifier.citationSzilagyi, P. and Lutz, M. and Gascon, J. and Juan-Alcaniz, J. and Esch, J. and Kapteijn, F. and Geerlings, H. et al. 2013. MOF@MOF core–shell vs. Janus particles and the effect of strain: potential for guest sorption, separation and sequestration. CrystEngComm. 15: pp. 6003-6008.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/49146
dc.identifier.doi10.1039/c3ce40653a
dc.description.abstract

The effect of strain on core-shell MOFcore@MOFshell particles is discussed and compared with that observed for analogous Janus particles. Whereas Janus particles do not display any effect of strain, the core of fully coated core-shell particles collapsed upon the formation of the outer shell, leaving the core inaccessible for guest adsorption. This suggests that Janus particles might become ideal candidates for gas separation, while core-shell particles could play a key role in sequestration of guest molecules.

dc.publisherThe Royal Society of Chemistry
dc.subjectmethane
dc.subjectchemistry
dc.subjecthydrogen storage
dc.subjectfabrication
dc.subjectMetal-organice frameworks
dc.subjectcoordination polymer crystals
dc.subjectadsorption
dc.subjectfunctionalization
dc.subjectdesign
dc.subjectporosity
dc.titleMOF@MOF core–shell vs. Janus particles and the effect of strain: potential for guest sorption, separation and sequestration
dc.typeJournal Article
dcterms.source.volume15
dcterms.source.startPage6003
dcterms.source.endPage6008
dcterms.source.issn14668033
dcterms.source.titleCrystEngComm
curtin.departmentDelft University of Technology
curtin.accessStatusFulltext not available


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