Exploring the influence of organic species on pre- and post-nucleation calcium carbonate
MetadataShow full item record
Organic additives are well known to influence the nucleation and growth of minerals. A combination of experimental and theoretical methods has been used to probe how three simple additives, containing varying numbers of carboxylate groups, influence the early stages of the growth of calcium carbonate. Computationally, the free energy landscape has been examined for each additive binding to Ca2+, the calcium carbonate ion pair, the surface of an amorphous calcium carbonate nanoparticle, and the basal plane of calcite. The different influence of the three organic ligands on the early stages of growth of calcium carbonate observed experimentally can be rationalised in terms of the degree of association of each anion with the species present prior to, and immediately after nucleation.
Showing items related by title, author, creator and subject.
Goh, Ching Yong (2012)A selection of amino acid functionalised calixarenes was studied. Acidic amino acid functionalised calixarenes were investigated as crystal growth modifiers. The self-assembly behaviour of proline functionalised ...
Raiteri, Paolo; Demichelis, Raffaella; Gale, Julian; Kellermeier, M.; Gebauer, D.; Quigley, D.; Wright, L.; Walsh, T. (2012)Organic additives arewellknownto influence the nucleation and growth ofminerals.Acombination of experimental and theoreticalmethods has been used to probe howthree simple additives, containing varying numbers of carboxylate ...
Nasir, Subriyer (2007)Reverse Osmosis (RO) is widely accepted as an alternative method to produce freshwater from different feed water sources. This technology competitively substitutes the thermal processes in the near future because of several ...