Changes in physicochemical and transport properties of a reverse osmosis membrane exposed to chloraminated seawater
MetadataShow full item record
This study contributed to improving our understanding of how disinfectants, applied to control biofouling of reverse osmosis (RO) membranes, result in membrane performance degradation. We investigated changes in physicochemical properties and permeation performance of a RO membrane with fully aromatic polyamide (PA) active layer. Membrane samples were exposed to varying concentrations of monochloramine, bromide, and iodide in both synthetic and natural seawater. Elemental analysis of the membrane active layer by Rutherford backscattering spectrometry (RBS) revealed the incorporation of bromine and iodine into the polyamide. The kinetics of polyamide bromination were first order with respect to the concentration of the secondary oxidizing agent Br2 for the conditions investigated. Halogenated membranes were characterized after treatment with a reducing agent and heavy ion probes to reveal the occurrence of irreversible ring halogenation and an increase in carboxylic groups, the latter produced as a result of amide bond cleavage. Finally, permeation experiments revealed increases in both water permeability and salt passage as a result of oxidative damage.
Showing items related by title, author, creator and subject.
Saeed, Asim (2012)Among different types of membrane modules used for cross flow filtration processes, Spiral Wound Module (SWM) dominates in the area of Ultra Filtration (UF), Nano Filtration (NF) and RO (Reverse Osmosis) due to high packing ...
Nasir, Subriyer (2007)Reverse Osmosis (RO) is widely accepted as an alternative method to produce freshwater from different feed water sources. This technology competitively substitutes the thermal processes in the near future because of several ...
Rajaeian, Babak (2012)Thin film composite (TFC) membranes have long been used by many large-scale applications (i.e., water and wastewater treatment). Recently, conventional polymeric TFC membranes are facing with short longevity due to high ...