Synthesis, Chemistry and Structure of Some 1,1-Dimethylcyclopropazulenes
| dc.contributor.author | Payne, Alan | |
| dc.contributor.author | Skelton, B. | |
| dc.contributor.author | White, A. | |
| dc.contributor.author | Wege, D. | |
| dc.date.accessioned | 2017-03-15T22:24:01Z | |
| dc.date.available | 2017-03-15T22:24:01Z | |
| dc.date.created | 2017-03-08T06:39:35Z | |
| dc.date.issued | 2016 | |
| dc.identifier.citation | Payne, A. and Skelton, B. and White, A. and Wege, D. 2016. Synthesis, Chemistry and Structure of Some 1,1-Dimethylcyclopropazulenes. Chemistry Select. 1 (16): pp. 5339-5346. | |
| dc.identifier.uri | http://hdl.handle.net/20.500.11937/50398 | |
| dc.identifier.doi | 10.1002/slct.201601168 | |
| dc.description.abstract |
1,1-Dimethylcycloprop[e]azulene and 1,1-dimethylcyclo-prop[f]azulene derivatives were prepared through a short syn-thesis from thiophene-1,1-dioxides using a Houk-Leaver azu-lene synthesis. The strain caused by the fusion of thecyclopropane ring had no effect on electrophilic aromatic sub-stitution reactions. X-ray structures of these compoundsshowed that cycloprop[e] azulenes have no or very small straininduced bond localisation, whereas cycloprop[f]azulene showssome minor localisation. | |
| dc.title | Synthesis, Chemistry and Structure of Some 1,1-Dimethylcyclopropazulenes | |
| dc.type | Journal Article | |
| dcterms.source.volume | 1 | |
| dcterms.source.number | 16 | |
| dcterms.source.startPage | 5339 | |
| dcterms.source.endPage | 5346 | |
| dcterms.source.title | Chemistry Select | |
| curtin.department | Department of Chemistry | |
| curtin.accessStatus | Fulltext not available |
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