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    The effect of weathering on U-Th-Pb and oxygen isotope systems of ancient zircons from the Jack Hills, Western Australia

    Access Status
    Fulltext not available
    Authors
    Pidgeon, Robert
    Nemchin, Alexander
    Whitehouse, M.
    Date
    2017
    Type
    Journal Article
    
    Metadata
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    Citation
    Pidgeon, R. and Nemchin, A. and Whitehouse, M. 2017. The effect of weathering on U-Th-Pb and oxygen isotope systems of ancient zircons from the Jack Hills, Western Australia. Geochimica Et Cosmochimica Acta. 197: pp. 142-166.
    Source Title
    Geochimica Et Cosmochimica Acta
    DOI
    10.1016/j.gca.2016.10.005
    ISSN
    0016-7037
    School
    Department of Applied Geology
    URI
    http://hdl.handle.net/20.500.11937/51021
    Collection
    • Curtin Research Publications
    Abstract

    © 2016 Elsevier LtdWe report the result of a SIMS U-Th-Pb and O-OH study of 44 ancient zircons from the Jack Hills in Western Australia with ages ranging from 4.3 Ga to 3.3 Ga. We have investigated the behaviour of oxygen isotopes and water in the grains by determining d18O and OH values at a number of locations on the polished surfaces of each grain. We have divided the zircons into five groups on the basis of their U-Th-Pb and OH-oxygen isotopic behaviour. The first group has concordant U-Th-Pb ages, minimal common Pb, d18O values consistent with zircons derived from mantle source rocks and no detectable OH content. U-Th-Pb systems in zircons from Groups 2, 3 and 4 vary from concordant to extremely discordant where influenced by cracks. Discordia intercepts with concordia at approximately zero Ma age are interpreted as disturbance of the zircon U-Th-Pb systems by weathering solutions during the extensive, deep weathering that has affected the Archean Yilgarn Craton of Western Australia since at least the Permian. Weathering solutions entering cracks have resulted in an influx of Th and U. d18O values of Group 2 grains fall approximately within the “mantle” range and OH is within background levels or slightly elevated. d18O values of Group 3 grains are characterised by an initial trend of decreasing d18O with increasing OH content. With further increase in OH this trend reverses and d18O becomes heavier with increasing OH. Group 4 grains have a distinct trend of increasing d18O with increasing OH. These trends are explained in terms of the reaction of percolating water with the metamict zircon structure and appear to be independent of analytical overlap with cracks. Group five zircons are characterised by U-Pb systems that appear to consist of more than one age but show only minor U-Pb discordance. Nevertheless trends in d18O versus OH in this group of grains resemble trends seen in the other groups. The observed trends of d18O with OH in the Jack Hills zircons are similar to those reported in a previous study of zircons from an Archean granite from south-western Australia.

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