Self-assembly in casting solutions of block copolymer membranes
| dc.contributor.author | Marques, D. | |
| dc.contributor.author | Vainio, U. | |
| dc.contributor.author | Chaparro, N. | |
| dc.contributor.author | Calo, Victor | |
| dc.contributor.author | Bezahd, A. | |
| dc.contributor.author | Pitera, J. | |
| dc.contributor.author | Peinemann, K. | |
| dc.contributor.author | Nunes, S. | |
| dc.date.accessioned | 2017-03-24T11:53:14Z | |
| dc.date.available | 2017-03-24T11:53:14Z | |
| dc.date.created | 2017-03-23T06:59:54Z | |
| dc.date.issued | 2013 | |
| dc.identifier.citation | Marques, D. and Vainio, U. and Chaparro, N. and Calo, V. and Bezahd, A. and Pitera, J. and Peinemann, K. et al. 2013. Self-assembly in casting solutions of block copolymer membranes. Soft Matter. 9 (23): pp. 5557-5564. | |
| dc.identifier.uri | http://hdl.handle.net/20.500.11937/51431 | |
| dc.identifier.doi | 10.1039/c3sm27475f | |
| dc.description.abstract |
Membranes with exceptional pore regularity and high porosity were obtained from block copolymer solutions. We demonstrate by small-angle X-ray scattering that the order which gives rise to the pore morphology is already incipient in the casting solution. Hexagonal order was confirmed in PS-b-P4VP 175k-b-65k solutions in DMF/THF/dioxane with concentrations as high as 24 wt%, while lamellar structures were obtained in more concentrated solutions in DMF or DMF/dioxane. The change in order has been understood with the support of dissipative particle dynamic modeling. © 2013 The Royal Society of Chemistry. | |
| dc.publisher | RSC Publishing | |
| dc.title | Self-assembly in casting solutions of block copolymer membranes | |
| dc.type | Journal Article | |
| dcterms.source.volume | 9 | |
| dcterms.source.number | 23 | |
| dcterms.source.startPage | 5557 | |
| dcterms.source.endPage | 5564 | |
| dcterms.source.issn | 1744-683X | |
| dcterms.source.title | Soft Matter | |
| curtin.department | Department of Applied Geology | |
| curtin.accessStatus | Fulltext not available |
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