Effect of ferrous iron on the nucleation and growth of CaCO3 in slightly basic aqueous solutions
MetadataShow full item record
The precipitation of calcium carbonate, CaCO3 and the growth of calcite has been studied in aqueous solutions containing ferrous iron (Fe2+). Two different types of bulk experiments have been carried out: nucleation experiments at constant pH, following the procedure developed by Gebauer et al. (2008), revealed the stabilisation of aragonite induced by the presence of the foreign ions at the expense of calcite and vaterite. Growth experiments, using the constant composition method (Tomson and Nancollas, 1978), clearly showed that calcite growth is inhibited by the presence of Fe2+ and the characterisation of the re-grown calcite crystals by HR-TEM confirmed the predictions obtained with molecular dynamics simulations. Additionally, in situ atomic force microscopy (AFM) flow-through growth experiments directly showed the distortion of the normal calcite growth spirals that lead to macroscopic inhibition of calcite growth. Finally, thermodynamic considerations for the solid solution-aqueous solution system Ca-Fe-CO2-H2O are discussed that allow the modelling of geochemical processes involved in this system, such as geological carbon storage in basaltic rocks.
Showing items related by title, author, creator and subject.
Vavouraki, A.; Putnis, Christine; Putnis, Andrew; Koutsoukos, P. (2008)In situ atomic force microscopy (AFM) has been used to compare the growth of pure calcite and the growth of calcite in the presence of sulfate ions from aqueous solutions at a constant value of supersaturation (S.I. = ...
Heberling, F.; Vinograd, V.; Polly, R.; Gale, Julian; Heck, S.; Rothe, J.; Bosbach, D.; Geckeis, H.; Winkler, B. (2014)Selenium is an environmentally relevant trace element, while the radioisotope 79Se is of particular concern in the context of nuclear waste disposal safety. Oxidized selenium species are relatively soluble and show only ...
Stockmann, G.; Wolff-Boenisch, Domenik; Bovet, N.; Gislason, S.; Oelkers, E. (2014)The aim of this study is to illuminate how calcite precipitation depends on the identity and structure of the growth substrate. Calcite was precipitated at 25 °C from supersaturated aqueous solutions in the presence of ...