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dc.contributor.authorVeder, Jean-pierre
dc.contributor.authorHorne, M.
dc.contributor.authorRüther, T.
dc.contributor.authorBond, A.
dc.contributor.authorRodopoulos, T.
dc.date.accessioned2017-04-28T13:56:56Z
dc.date.available2017-04-28T13:56:56Z
dc.date.created2017-04-28T09:06:11Z
dc.date.issued2012
dc.identifier.citationVeder, J. and Horne, M. and Rüther, T. and Bond, A. and Rodopoulos, T. 2012. Favourable surface properties of boron-doped diamond electrodes for aluminium electrodeposition from ionic liquids. Electrochemistry Communications. 18 (1): pp. 85-87.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/51941
dc.identifier.doi10.1016/j.elecom.2012.02.018
dc.description.abstract

Aluminium electrodeposition on a boron-doped diamond (BDD) electrode was studied in the ionic liquid: 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, [C 4mpyr][NTf 2]. Cyclic voltammograms recorded on BDD electrodes in 1 m solutions of AlCl 3 in [C 4mpyr][NTf 2] were compared with those recorded on Au, Al and glassy carbon (GC) electrodes. The BDD electrode exhibits similar voltammetric responses for Al electrodeposition as on metallic electrodes but without interferences from alloy formation or reaction of the electrode material. Conversely, nucleation and growth of Al is significantly more difficult on freshly abraded GC. The electrochemical stability and activity of BDD over a wide potential range make it a highly favourable surface for studying metal deposition at very negative potentials in ionic liquids. © 2012 Elsevier B.V.

dc.publisherElsevier Inc.
dc.titleFavourable surface properties of boron-doped diamond electrodes for aluminium electrodeposition from ionic liquids
dc.typeJournal Article
dcterms.source.volume18
dcterms.source.number1
dcterms.source.startPage85
dcterms.source.endPage87
dcterms.source.issn1388-2481
dcterms.source.titleElectrochemistry Communications
curtin.departmentDepartment of Physics and Astronomy
curtin.accessStatusFulltext not available


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