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dc.contributor.authorVeder, Jean-pierre
dc.contributor.authorHorne, M.
dc.contributor.authorRüther, T.
dc.contributor.authorBond, A.
dc.contributor.authorRodopoulos, T.
dc.date.accessioned2017-04-28T13:57:47Z
dc.date.available2017-04-28T13:57:47Z
dc.date.created2017-04-28T09:06:11Z
dc.date.issued2013
dc.identifier.citationVeder, J. and Horne, M. and R�ther, T. and Bond, A. and Rodopoulos, T. 2013. Aluminium oxidation at high anodic potentials in an AlCl <inf>3</inf>-containing air- and water-stable ionic liquid solution. Electrochemistry Communications. 37: pp. 68-70.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/52161
dc.identifier.doi10.1016/j.elecom.2013.10.015
dc.description.abstract

The observation of a multi-step stripping process at high positive potentials is reported for aluminium electrodeposition from a solution of AlCl3 in the air- and water-stable ionic liquid 1-butyl-1- methylpyrrolidinium bis(trifluoromethylsulfonyl)imide. Cyclic voltammograms recorded on an aluminium-coated boron-doped diamond electrode revealed complex oxidative behaviour, suggesting that a passive layer forms on the freshly deposited aluminium that hinders electro-oxidation. High positive potentials are required to induce chloride attack of the passive film, composed of Al-NTf 2 compounds, and facilitate the rapid oxidation of the underlying aluminium metal. These results have important implications in bipolar-pulse electroplating and electrorefining applications where electrodissolution of aluminium is required. © 2013 Published by Elsevier B.V. All rights reserved.

dc.publisherElsevier Inc.
dc.titleAluminium oxidation at high anodic potentials in an AlCl <inf>3</inf>-containing air- and water-stable ionic liquid solution
dc.typeJournal Article
dcterms.source.volume37
dcterms.source.startPage68
dcterms.source.endPage70
dcterms.source.issn1388-2481
dcterms.source.titleElectrochemistry Communications
curtin.departmentDepartment of Physics and Astronomy
curtin.accessStatusFulltext not available


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