Curtin University Homepage
  • Library
  • Help
    • Admin

    espace - Curtin’s institutional repository

    JavaScript is disabled for your browser. Some features of this site may not work without it.
    View Item 
    • espace Home
    • espace
    • Curtin Research Publications
    • View Item
    • espace Home
    • espace
    • Curtin Research Publications
    • View Item

    Modulating oxone-MnOx/silica catalytic systems towards ibuprofen degradation: Insights into system effects, reaction kinetics and mechanisms

    Access Status
    Fulltext not available
    Authors
    Yang, J.
    Yuan, B.
    Cui, H.
    Wang, Shaobin
    Fu, M.
    Date
    2017
    Type
    Journal Article
    
    Metadata
    Show full item record
    Citation
    Yang, J. and Yuan, B. and Cui, H. and Wang, S. and Fu, M. 2017. Modulating oxone-MnOx/silica catalytic systems towards ibuprofen degradation: Insights into system effects, reaction kinetics and mechanisms. Applied Catalysis B: Environmental. 205: pp. 327-339.
    Source Title
    Applied Catalysis B: Environmental
    DOI
    10.1016/j.apcatb.2016.12.046
    ISSN
    0926-3373
    School
    Department of Chemical Engineering
    URI
    http://hdl.handle.net/20.500.11937/52468
    Collection
    • Curtin Research Publications
    Abstract

    © 2016 Elsevier B.V.Heterogeneous processes activated persulfate for organic degradation is increasingly recognized as an environmentally important remediation technology. However, manipulating persulfate oxidation processes with desirable decontamination effectiveness is still underdeveloped. Towards this goal, we systematically investigated the catalytic behaviors of Oxone-MnOx/silica systems towards aqueous ibuprofen (IBU) degradation in terms of system effects, reaction kinetics and mechanisms. MnOx/SBA-15 (MS) demonstrated variable catalytic Oxone efficacies towards IBU removal at different solution pHs. Meanwhile, the catalyst supports and FeOx co-doping within MS also produced significant impacts on catalytic Oxone efficacy. Moreover, the catalytic Oxone efficacies of MS for IBU degradation were generally inhibited by humic acid, NO3-, HCO3-, SO42- and PO43- to different extents at low/high levels. Interestingly, Cl- at low concentrations (2 mM) obviously inhibited IBU removal by Oxone-MS, while Cl- at high concentrations (20 mM) greatly enhanced IBU removal. Kinetic studies implied that IBU removal by Oxone-MnOx/silica systems using two first-order kinetic models was closely related to the extents of the interferences of synthetic conditions and water chemistry components. The surface electron transfer between [tbnd]MnOx(OH)y species of MS and HSO5- of Oxone was responsible for the formation of reactive oxygen radicals, thus contributing to IBU degradation. Liquid chromatography–mass spectrometry was employed to identify oxidation products of IBU, and reaction pathways of IBU oxidation were accordingly proposed.

    Related items

    Showing items related by title, author, creator and subject.

    • Egg-shaped core/shell α-Mn2O3@α-MnO2 as heterogeneous catalysts for decomposition of phenolics in aqueous solutions
      Saputra, E.; Zhang, H.; Liu, Q.; Sun, Hongqi; Wang, S. (2016)
      Novel uniform ellipsoid a-Mn2O3@a-MnO2 core/shell (McMs) nanocomposites were prepared via a hydrothermal process with a shape-control protocol followed by calcination at different temperatures. The properties of the ...
    • Synthesis of Co oxide doped carbon aerogel catalyst and catalytic performance in heterogeneous oxidation of phenol in water
      Hardjono, Yasnessya; Sun, Hongqi; Tian, Hu-Yong; Buckley, Craig; Wang, Shaobin (2011)
      Co oxide doped carbon aerogel (Co/CA) was prepared, characterised by several techniques, and tested for heterogeneous oxidation of phenol in aqueous solution using oxone as an oxidant. For a comparison, homogeneous oxidation ...
    • Red mud and fly ash supported Co catalysts for phenol oxidation
      Saputra, Edy; Muhammad, Syaifullah; Sun, Hongqi; Ang, Ming; Tade, Moses; Wang, Shaobin (2012)
      Industrial wastes, red mud (RM) and fly ash (FA), were employed as supports for synthesis of Co-oxide based catalysts. Co/RM and Co/FA were characterised by X-ray diffraction (XRD), scanning electron microscopy coupling ...
    Advanced search

    Browse

    Communities & CollectionsIssue DateAuthorTitleSubjectDocument TypeThis CollectionIssue DateAuthorTitleSubjectDocument Type

    My Account

    Admin

    Statistics

    Most Popular ItemsStatistics by CountryMost Popular Authors

    Follow Curtin

    • 
    • 
    • 
    • 
    • 

    CRICOS Provider Code: 00301JABN: 99 143 842 569TEQSA: PRV12158

    Copyright | Disclaimer | Privacy statement | Accessibility

    Curtin would like to pay respect to the Aboriginal and Torres Strait Islander members of our community by acknowledging the traditional owners of the land on which the Perth campus is located, the Whadjuk people of the Nyungar Nation; and on our Kalgoorlie campus, the Wongutha people of the North-Eastern Goldfields.