The influence of thermal degradation on the electrodeposition of aluminium from an air- and water-stable ionic liquid
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Authors
Veder, Jean-pierre
Horne, M.
Rüther, T.
Bond, A.
Rodopoulos, T.
Date
2013Type
Journal Article
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Veder, J. and Horne, M. and Rüther, T. and Bond, A. and Rodopoulos, T. 2013. The influence of thermal degradation on the electrodeposition of aluminium from an air- and water-stable ionic liquid. Physical Chemistry Chemical Physics. 15 (20): pp. 7470-7474.
Source Title
Physical Chemistry Chemical Physics
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School
Department of Physics and Astronomy
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Abstract
Aluminium electrodeposition is demonstrated from a thermally degraded ionic liquid solution. NMR and voltammetric analyses established that Al3+ reduction was remarkably similar to that in non-degraded IL solutions suggesting that the electroactive metal-containing species was unaffected by heat treatment. Electron microscopy revealed a significant grain refinement of the deposited metal. © the Owner Societies 2013.