Prenucleation clusters and non-classical nucleation
|dc.identifier.citation||Gebauer, D. and Cölfen, H. 2011. Prenucleation clusters and non-classical nucleation. Nano Today. 6 (6): pp. 564-584.|
In this contribution, we review the recent literature on an alternative crystallization pathway involving stable clusters prior to nucleation and show that the prenucleation cluster pathway is a truly non-classical concept of nucleation. Prenucleation clusters are solutes with "molecular" character in aqueous solution. It becomes evident that the stable clusters may have been concealed by the so-called ion pair concept and activity effects. We show that non-classical nucleation via stable prenucleation clusters is a highly valuable concept for a novel understanding of phenomena observed in bio- and biomimetic mineralization, which however may hardly be rationalized by means of classical nucleation theory. The importance to combine experimental and theoretical studies is emphasized. © 2011 Elsevier Ltd.
|dc.title||Prenucleation clusters and non-classical nucleation|
|curtin.department||Department of Chemistry|
|curtin.accessStatus||Fulltext not available|
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