Mercury complexes of an N-heterocyclic carbene derived from a calixarene/azolium cyclophane hybrid
MetadataShow full item record
© Springer Science+Business Media Dordrecht 2015.Reaction of mercuric acetate with an imidazolium-linked cyclophane incorporating 2,6-phenolic moieties results in formation of an interesting new N-heterocyclic carbene (NHC) complex of mercury. The new complex is cationic and binuclear, incorporating two mercury centres and two bis(NHC) ligands, each mercury atom being bound by two NHC moieties and two phenol/phenoxy moieties. Forms of the complex having coordinating ((Formula presented.))and non-coordinating ((Formula presented.))counterions have been structurally characterised.
Showing items related by title, author, creator and subject.
Mercury complexes of N-heterocyclic carbenes derived from imidazolium-linked cyclophanes: synthesis, structure, and reactivityBaker, M. V.; Brown, David; Haque, R. A.; Simpson, P. V.; Skelton, B. W.; White, A. H.; Williams, C. C. (2009)A range of mercury-imidazolylidene complexes have been prepared by reaction of imidazolium-linked cyclophanes with mercury(II) acetate. For cyclophanes based on meta-xylyl groups the mercury complexes are mononuclear and ...
Baker, M.; Brown, David; Haque, R.; Skelton, B.; White, A. (2009)Mononuclear silver and mercury complexes bearing bis-N-heterocyclic carbene (NHC) ligands withlinear coordination modes have been prepared and structurally characterised. The complexes form metallocyclic structures that ...
A comprehensive pore structure study of the Bakken Shale with SANS, N2 adsorption and mercury intrusionLiu, K.; Ostadhassan, M.; Sun, L.; Zou, J.; Yuan, Yujie; Gentzis, T.; Zhang, Y.; Carvajal-Ortiz, H.; Rezaee, Reza (2019)Small angle neutron scattering (SANS) analysis was performed on six Bakken Shale samples with different maturities to reveal the complexities in the pore structure. Pore size distribution (PSD), porosity and specific ...