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Controlling embedment and surface chemistry of nanoclusters in metal-organic frameworks

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Open access
Authors
Coupry, D.
Butson, J.
Petkov, P.
Saunders, M.
O'Donnell, K.
Kim, H.
Buckley, Craig
Addicoat, M.
Heine, T.
Szilagyi, P.
Date
2016
Type
Journal Article

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Coupry, D. and Butson, J. and Petkov, P. and Saunders, M. and O'Donnell, K. and Kim, H. and Buckley, C. et al. 2016. Controlling embedment and surface chemistry of nanoclusters in metal-organic frameworks. ChemComm. 52 (29): pp. 5175-5178.
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ChemComm
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Department of Physics and Astronomy
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Abstract

A combined theoretical and experimental approach demonstrates that nanocluster embedment into the pores of metal–organic frameworks (MOF) may be influenced by the chemical functionalisation of the MOF. Furthermore, this results in the surface functionalisation of the embedded nanoclusters, highlighting the potential of MOF scaffolds for the design and synthesis of novel functional materials.

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