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    Phase transition and volume expansion in CO2-expanded liquid systems

    Access Status
    Fulltext not available
    Authors
    Denardin, F.
    Vieira De Melo, S.
    Mammucari, R.
    Foster, Neil
    Date
    2013
    Type
    Conference Paper
    
    Metadata
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    Citation
    Denardin, F. and Vieira De Melo, S. and Mammucari, R. and Foster, N. 2013. Phase transition and volume expansion in CO2-expanded liquid systems, pp. 529-534.
    Source Title
    Chemical Engineering Transactions
    DOI
    10.3303/CET1332089
    ISSN
    2283-9216
    School
    Department of Chemical Engineering
    URI
    http://hdl.handle.net/20.500.11937/55285
    Collection
    • Curtin Research Publications
    Abstract

    Binary mixtures of conventional solvents are very useful in the dense gas processing of pharmaceuticals. However, the lack of experimental data for ternary systems of organic solvents and dense carbon dioxide hinders the full exploitation of solvent engineering for particle formation by dense gas processing. In this work, volume expansion and mixture critical points for binary and ternary systems of organic solvents and carbon dioxide were experimentally determined at different temperatures and pressures. Results show an exponential behavior of the liquid volume expansion with pressure as the mixture come close to the mixture critical point. Copyright © 2013, AIDIC Servizi S.r.l.

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