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dc.contributor.authorDong, Li
dc.contributor.authorGeng, C.
dc.contributor.authorJiao, P.
dc.date.accessioned2017-08-24T02:19:52Z
dc.date.available2017-08-24T02:19:52Z
dc.date.created2017-08-23T07:21:48Z
dc.date.issued2015
dc.identifier.citationDong, L. and Geng, C. and Jiao, P. 2015. Silyl Nitronate Cycloadditions Catalyzed by Cu(II)-Bisoxazoline. Journal of Organic Chemistry. 80 (21): pp. 10992-11002.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/55659
dc.identifier.doi10.1021/acs.joc.5b02035
dc.description.abstract

© 2015 American Chemical Society. Cu(OTf) 2 and chiral BOX ligand-catalyzed 1,3-dipolar cycloadditions of triisopropylsilyl nitronates with a,ß-unsaturated carboximides produced chiral isoxazolines in high yields, high enantioselectivities, and complete diastereoselectivities. These chiral isoxazoline products were further converted into structurally diversified derivatives, which demonstrated the utility of the new method of constructing isoxazolines. The transition-state structure of cycloaddition was proposed in the light of the relative and absolute configurations of the products.

dc.publisherAmerican Chemical Society
dc.titleSilyl Nitronate Cycloadditions Catalyzed by Cu(II)-Bisoxazoline
dc.typeJournal Article
dcterms.source.volume80
dcterms.source.number21
dcterms.source.startPage10992
dcterms.source.endPage11002
dcterms.source.issn0022-3263
dcterms.source.titleJournal of Organic Chemistry
curtin.departmentFuels and Energy Technology Institute
curtin.accessStatusFulltext not available


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