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dc.contributor.authorGong, X.
dc.contributor.authorZhang, Shu
dc.date.accessioned2017-11-24T05:26:01Z
dc.date.available2017-11-24T05:26:01Z
dc.date.created2017-11-24T04:48:52Z
dc.date.issued2017
dc.identifier.citationGong, X. and Zhang, S. 2017. Changes in char structure due to inorganic matters during anthracite pyrolysis. Journal of Analytical and Applied Pyrolysis. 127: pp. 170-175.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/58494
dc.identifier.doi10.1016/j.jaap.2017.08.011
dc.description.abstract

© 2017 Elsevier B.V. To understand effects of inherent mineral matters on the evolution of char structure, the microcrystalline structures of chars from the pyrolysis of raw, HCl-washed (CW) and HCl & HF-washed anthracites (CFW) were investigated by X-ray diffraction (XRD) respectively. Stacking height (Lc), interlayer spacing (d 002 ) and crystallite width (La) were used as parameters for char structure estimation. The results showed that with increasing contents of inherent mineral matters, Lc of char decreased, whereas d 002 and La increased. To study effects of a single inorganic matter, CFW was impregnated with Al 2 O 3 , SiO 2 , and CaO respectively. It was found that all of them (oxides) have resulted in the decrease in Lc and increase in La and d 002 . Differing from Al 2 O 3 , SiO 2 , and CaO, the introduction of Fe 2 O 3 has caused the reduction for both La and Lc values simultaneously, especially when the Fe 2 O 3 contents in the coal were high.

dc.publisherElsevier
dc.titleChanges in char structure due to inorganic matters during anthracite pyrolysis
dc.typeJournal Article
dcterms.source.volume127
dcterms.source.startPage170
dcterms.source.endPage175
dcterms.source.issn0165-2370
dcterms.source.titleJournal of Analytical and Applied Pyrolysis
curtin.departmentSchool of Chemical and Petroleum Engineering
curtin.accessStatusFulltext not available


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