Macroporous platinum electrodes for hydrogen oxidation in ionic liquids
MetadataShow full item record
Macroporous platinum structures have been prepared by electrodeposition in the interstitial spaces between a 500 nm polystyrene sphere template, onto platinum and glassy carbon electrodes. The structures were analysed with scanning electron microscopy and confocal microscopy. These electrodes are employed for the electrochemical oxidation of hydrogen in the room temperature ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C 2 mim][NTf 2 ]). The behaviour on the porous electrodes showed obvious thin-layer characteristics in the cyclic voltammetry, with a strong tendency for hydrogen to accumulate and remain in the pores after being removed from the cell. Plots of peak current vs concentration (10–100% H 2 ) were linear, but currents continued to increase over time. The sensitivities (gradients) of the calibration plots were the highest for the platinum porous structures (compared to the bare, or nanoparticle-modified surfaces). Due to the accumulation of gas, such modified electrodes could be employed as leak-detectors for very low concentrations of hydrogen.
Showing items related by title, author, creator and subject.
Fast responding hydrogen gas sensors using platinum nanoparticle modified microchannels and ionic liquidsHussain, Ghulam; Ge, M.; Zhao, C.; Silvester-Dean, Debbie (2019)© 2019 Elsevier B.V. From a safety perspective, it is vital to have fast responding gas sensors for toxic and explosive gases in the event of a gas leak. Amperometric gas sensors have been developed for such a purpose, ...
Wandt, Johannes; Lee, Wade; Arrigan, Damien; Silvester, Debbie (2018)We report on the development of a very simple and robust reference electrode suitable for use in room temperature ionic liquids, that can be employed with planar devices. The reference electrode is based on LiFePO4(LFP), ...
The electrochemical oxidation of hydrogen at activated platinum electrodes in room temperature ionic liquids as solventsSilvester, Debbie; Ward, K.; Aldous, L.; Hardacre, C.; Compton, R. (2008)The oxidation of hydrogen was studied at an activated platinum micro-electrode by cyclic voltammetry in the following ionic liquids: [C2mim][NTf2], [C4mim][NTf2], [N6,2,2,2][NTf2], [P14,6,6,6][NTf2], [C4mim][OTf], ...