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    Development of Surface-Modified Microelectrode Arrays for the Electrochemical Detection of Dihydrogen Phosphate

    Access Status
    Fulltext not available
    Authors
    Berduque, A.
    Herzog, G.
    Watson, Y.
    Arrigan, Damien
    Moutet, J.
    Reynes, O.
    Royal, G.
    Saint-Aman, E.
    Date
    2005
    Type
    Journal Article
    
    Metadata
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    Citation
    Berduque, A. and Herzog, G. and Watson, Y. and Arrigan, D. and Moutet, J. and Reynes, O. and Royal, G. et al. 2005. Development of Surface-Modified Microelectrode Arrays for the Electrochemical Detection of Dihydrogen Phosphate. Electroanalysis. 17 (5-6): pp. 392-399.
    Source Title
    Electroanalysis
    DOI
    10.1002/elan.200403184
    Additional URLs
    http://onlinelibrary.wiley.com/doi/10.1002/elan.200403184/pdf
    ISSN
    1040-0397
    URI
    http://hdl.handle.net/20.500.11937/6008
    Collection
    • Curtin Research Publications
    Abstract

    Platinum and gold microelectrode arrays (MEAs), fabricated on silicon substrates with different geometric characteristics, were surface-modified by the potentiostatic electropolymerization of the pyrrole-ferrocene derivative Py(CH2)3NHCOFc, in the case of the platinum MEAs, and chemisorption of the thiol-functionalized ferrocene HS(CH2)6Nþ(CH3)2Fc, in the case of the gold MEAs. Cyclic voltammetry of these MEAs was typical of thin film behavior. The modified MEAs were investigated for the detection of the dihydrogen phosphate mono-anion in nonaqueous media via differential pulse voltammetry. This was based on electrostatic interaction and/or hydrogenbonding between the target anion and the amide-ferrocene or ammonium-ferrocene functionalized electrode surfaces. A decrease in the ferrocene (Fc) oxidation peak current with a concomitant increase in the peak current of a new peak at lower potentials was observed when the concentration of the dihydrogen phosphate was increased.

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