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    Low-energy electron-impact dissociative excitation of molecular hydrogen and its isotopologues

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    Authors
    Scarlett, L.
    Tapley, J.
    Fursa, Dmitry
    Zammit, M.
    Savage, J.
    Bray, Igor
    Date
    2017
    Type
    Journal Article
    
    Metadata
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    Citation
    Scarlett, L. and Tapley, J. and Fursa, D. and Zammit, M. and Savage, J. and Bray, I. 2017. Low-energy electron-impact dissociative excitation of molecular hydrogen and its isotopologues. Physical Review A. 96 (6): Article ID 062708.
    Source Title
    Physical Review A
    DOI
    10.1103/PhysRevA.96.062708
    ISSN
    2469-9926
    School
    School of Electrical Engineering, Computing and Mathematical Science (EECMS)
    URI
    http://hdl.handle.net/20.500.11937/61436
    Collection
    • Curtin Research Publications
    Abstract

    We apply the adiabatic nuclei convergent close-coupling method to electron-impact dissociative excitation of H2 in the low-energy regime. Differential and integrated cross sections are presented for excitation of the bSu+3 state, the primary pathway t o dissociation of H2 at low energies. Agreement with experiment is satisfactory. Results are also presented for the isotopologues D2, T2, HD, HT, and DT, which show a pronounced isotope effect near threshold in both the differential and integrated cross sections.

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