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dc.contributor.authorSöngen, H.
dc.contributor.authorReischl, Bernhard
dc.contributor.authorMiyata, K.
dc.contributor.authorBechstein, R.
dc.contributor.authorRaiteri, Paolo
dc.contributor.authorRohl, Andrew
dc.contributor.authorGale, Julian
dc.contributor.authorFukuma, T.
dc.contributor.authorKühnle, A.
dc.date.accessioned2018-05-18T07:57:47Z
dc.date.available2018-05-18T07:57:47Z
dc.date.created2018-05-18T00:23:15Z
dc.date.issued2018
dc.identifier.citationSöngen, H. and Reischl, B. and Miyata, K. and Bechstein, R. and Raiteri, P. and Rohl, A. and Gale, J. et al. 2018. Resolving Point Defects in the Hydration Structure of Calcite (10.4) with Three-Dimensional Atomic Force Microscopy. Physical Review Letters. 120 (11): Article ID 116101.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/67232
dc.identifier.doi10.1103/PhysRevLett.120.116101
dc.description.abstract

It seems natural to assume that defects at mineral surfaces critically influence interfacial processes such as the dissolution and growth of minerals in water. The experimental verification of this claim, however, is challenging and requires real-space methods with utmost spatial resolution, such as atomic force microscopy (AFM). While defects at mineral-water interfaces have been resolved in 2D AFM images before, the perturbation of the surrounding hydration structure has not yet been analyzed experimentally. In this Letter, we demonstrate that point defects on the most stable and naturally abundant calcite (10.4) surface can be resolved using high-resolution 3D AFM - even within the fifth hydration layer. Our analysis of the hydration structure surrounding the point defect shows a perturbation of the hydration with a lateral extent of approximately one unit cell. These experimental results are corroborated by molecular dynamics simulations.

dc.publisherThe American Physical Society
dc.titleResolving Point Defects in the Hydration Structure of Calcite (10.4) with Three-Dimensional Atomic Force Microscopy
dc.typeJournal Article
dcterms.source.volume120
dcterms.source.number11
dcterms.source.issn0031-9007
dcterms.source.titlePhysical Review Letters
curtin.note

© 2018 American Physical Society

curtin.departmentNanochemistry Research Institute
curtin.accessStatusOpen access


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