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    Solution phase and solid state studies of lanthanoid-calixarene bottlebrush clusters

    Phe R 2018.pdf (8.521Mb)
    Access Status
    Open access
    Authors
    Phe, Rene Zhi Hui
    Date
    2018
    Supervisor
    Prof. Mark Ogden
    Type
    Thesis
    Award
    PhD
    
    Metadata
    Show full item record
    Faculty
    Science and Engineering
    School
    Chemistry
    URI
    http://hdl.handle.net/20.500.11937/68324
    Collection
    • Curtin Theses
    Abstract

    The conditions required for formation of unusual bottlebrush-shaped lanthanoid coordination clusters were investigated. The known clusters are supported by tetrazole-functionalised p-t-butylcalixarenes, and carboxylate co-ligands. It was confirmed that the lighter lanthanoids form mononuclear complexes, and heavier lanthanoids form bottlebrush clusters. Changing the carboxylate co-ligand had little impact on the complexes formed. Altering the structure of the calixarene had a significant impact. When the t-butyl group was replaced with hydrogen or allyl groups, mononuclear complexes formed.

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