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    Variation of structural motifs in lanthanoid hydroxo clusters by ligand modification

    192002_192002.pdf (1.279Mb)
    Access Status
    Open access
    Authors
    Andrews, Philip
    Gee, W.
    Junk, Peter
    Massi, Massimiliano
    Date
    2013
    Type
    Journal Article
    
    Metadata
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    Citation
    Andrews, Philip C. and Gee, William J. and Junk, Peter C. and Massi, Massimiliano. 2013. Variation of structural motifs in lanthanoid hydroxo clusters by ligand modification. New Journal of Chemistry. 37: pp. 35-48.
    Source Title
    New Journal of Chemistry
    DOI
    10.1039/c2nj40560a
    ISSN
    1144-0546
    URI
    http://hdl.handle.net/20.500.11937/31397
    Collection
    • Curtin Research Publications
    Abstract

    The isolation of multinuclear lanthanoid clusters with different nuclearities and geometries commenced as a serendipitous discovery and is now the focus of intense research, not only from a coordination chemistry point of view, but also in a variety of applied fields. This perspective analyses the structural library of reported lanthanoid hydroxo clusters to find trends linking their structural motifs with factors such as the specific lanthanoid, the bulkiness of the outer shell of ligands, the coordinating nature of the ligands, and the synthetic methodology. While trends are indeed starting to appear, does this signify that the synthetic chemistry of lanthanoid clusters has now progressed from serendipity to a more rational approach?

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