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    Magnetic studies of metal ion coordination clusters encapsulated with thiacalixarene

    Access Status
    Fulltext not available
    Authors
    Fuller, Rebecca
    Livesey, K.
    Woodward, R.
    McKinley, A.
    Skelton, B.
    Koutsantonis, G.
    Date
    2014
    Type
    Journal Article
    
    Metadata
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    Citation
    Fuller, R. and Livesey, K. and Woodward, R. and McKinley, A. and Skelton, B. and Koutsantonis, G. 2014. Magnetic studies of metal ion coordination clusters encapsulated with thiacalixarene. Australian Journal of Chemistry. 67 (11): pp. 1588-1594.
    Source Title
    Australian Journal of Chemistry
    DOI
    10.1071/CH14136
    ISSN
    0004-9425
    School
    School of Molecular and Life Sciences (MLS)
    URI
    http://hdl.handle.net/20.500.11937/68539
    Collection
    • Curtin Research Publications
    Abstract

    © CSIRO 2014. Three thiacalix[4]arene polynuclear complexes have been prepared by literature methods for detailed magnetic investigation. The [Fe 3 O(L) 2 ] (LH 4 = thiacalix[4]arene) complex is found to exhibit interesting anti-ferromagnetic exchange coupling. Jahn-Teller distortion in [Cu 4 (L) 2 ] complex leads to strong anti-ferromagnetic coupling at low temperatures. The temperature-dependent susceptibility of the [(µ-H 2 O)Eu 2 (LH) 2 (DMF) 4 ] complex is well described by a ground state involving the thermal population of the lowest three excited states.

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