CFD model of a methane fuelled single cell SOFC stack for analysing the combined effects of macro/micro structural parameters
MetadataShow full item record
A fully coupled CFD model of a direct internal reforming single cell SOFC stack previously designed by Ceramic Fuel Cell Ltd (CFCL) has been developed. In this model, an innovative solution technique for accelerating finite volume treatment of the electrodes as two distinct layers, a diffusion layer and a catalyst layer, is taken to analyse the combined effects of the macro/microstructural parameters on distribution of fields and each of the reactions involved in the process. To assess the simulation results, the model is not only evaluated with the CFCL experimental data that was reported from the similar geometry, but it is also assessed for the effects of the reforming and water gas shift reactions. It is found that a 3D model is more representative of the global reforming reaction rate. Furthermore, distributions of the key parameters along different spatial domains disclose the complex interaction between the anode flow field design and microstructural parameters of the anode diffusion layer. In fact, an optimal set of the anode microstructure that promotes the reforming reaction rate will not automatically result in improved SOFC performance. The developed model is a powerful tool to study complex fuel cell related problems and to optimize fuel cells’ structure.
Showing items related by title, author, creator and subject.
In situ fabrication of (Sr,La)FeO<inf>4</inf> with CoFe alloy nanoparticles as an independent catalyst layer for direct methane-based solid oxide fuel cells with a nickel cermet anodeChang, H.; Chen, H.; Shao, Zongping; Shi, J.; Bai, J.; Li, S. (2016)© 2016 The Royal Society of Chemistry.An independent catalyst layer is applied to develop a highly effective way to reduce coking when operating in methane based fuels, in which the catalyst layer is separated from a Ni ...
Stable direct-methane solid oxide fuel cells with calcium-oxide-modified nickel-based anodes operating at reduced temperaturesQu, J.; Wang, W.; Chen, Y.; Deng, X.; Shao, Zongping (2016)In this study, some basic oxide additives are introduced into the conventional Ni–Ce0.8Sm0.2O1.9 (SDC) cermet anodes of solid oxide fuel cells (SOFCs) for using methane as the fuel. The effects of incorporating basic ...
Periasamy, Vijay ; Tadé, Moses; Shao, Zongping (2019)© 2019 Hydrogen Energy Publications LLC The electrode microstructure plays an important role in determining the performance of the Solid Oxide Fuel Cells (SOFCs). The conventional SOFC electrodes are based on two kinds ...