Show simple item record

dc.contributor.authorTan, D.
dc.contributor.authorMocerino, Mauro
dc.date.accessioned2018-06-29T12:27:30Z
dc.date.available2018-06-29T12:27:30Z
dc.date.created2018-06-29T12:08:45Z
dc.date.issued2018
dc.identifier.citationTan, D. and Mocerino, M. 2018. Distal functionalisation of C<inf>4</inf>symmetric tetramethoxyresorcinarene by selective lithiation. Journal of Inclusion Phenomena and Molecular Recognition in Chemistry. 91 (1-2): pp. 71-80.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/68858
dc.identifier.doi10.1007/s10847-018-0802-4
dc.description.abstract

© 2018, Springer Science+Business Media B.V., part of Springer Nature. Three novel C4symmetric O-substituted derivatives of tetramethoxyresorcinarene were synthesised and characterised and the selective distal lithiation of these derivatives was investigated. Lithiation of the tetraethoxy derivative, followed by quenching with dimethyldisulfide selectively afforded the distal product in 36% yield after removal of unreacted starting resorcinarene. Lithiation of the MOM derivative produced the five possible lithiated products, with the mono being the major product; the distally substituted derivative being a minor product. The benzyloxyresorcinarene appeared to be unstable under the lithation conditions. These results suggest that the selectivity of the distal lithation reaction is heavily dependent on the O-substituents of the resorcinarene.

dc.publisherKluwer Academic Publishers
dc.titleDistal functionalisation of C<inf>4</inf>symmetric tetramethoxyresorcinarene by selective lithiation
dc.typeJournal Article
dcterms.source.volume91
dcterms.source.number1-2
dcterms.source.startPage71
dcterms.source.endPage80
dcterms.source.issn0923-0750
dcterms.source.titleJournal of Inclusion Phenomena and Molecular Recognition in Chemistry
curtin.departmentSchool of Molecular and Life Sciences (MLS)
curtin.accessStatusFulltext not available


Files in this item

FilesSizeFormatView

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record