N-Hexane isomerisation: Exploit hydrogen spillover to reduce catalyst costs
dc.contributor.author | Shinde, Yogesh | |
dc.contributor.author | Chakraborty, M. | |
dc.contributor.author | Parikh, P. | |
dc.date.accessioned | 2018-06-29T12:29:06Z | |
dc.date.available | 2018-06-29T12:29:06Z | |
dc.date.created | 2018-06-29T12:08:53Z | |
dc.date.issued | 2017 | |
dc.identifier.citation | Shinde, Y. and Chakraborty, M. and Parikh, P. 2017. N-Hexane isomerisation: Exploit hydrogen spillover to reduce catalyst costs. Progress in Reaction Kinetics and Mechanism. 42 (1): pp. 62-69. | |
dc.identifier.uri | http://hdl.handle.net/20.500.11937/69267 | |
dc.identifier.doi | 10.3184/146867816X14764492607157 | |
dc.description.abstract |
We report the role of hydrogen spillover in n-hexane isomerisation over carbon nanotubes or SiC mixed with hierarchical zeolite beta. Here we infer that: (1) hydrogen spillover is a necessary step; (2) spilled-over H hydrogenates isomerised olefin at Brønsted acid sites only; and (3) closeness between acid and metal sites at the nanoscale enhances the rate of reaction, though this is not a requirement for this reaction to proceed. The economic advantage of the spillover phenomenon (necessitating less Pt on the catalyst) has been highlighted. | |
dc.title | N-Hexane isomerisation: Exploit hydrogen spillover to reduce catalyst costs | |
dc.type | Journal Article | |
dcterms.source.volume | 42 | |
dcterms.source.number | 1 | |
dcterms.source.startPage | 62 | |
dcterms.source.endPage | 69 | |
dcterms.source.issn | 1468-6783 | |
dcterms.source.title | Progress in Reaction Kinetics and Mechanism | |
curtin.department | Department of Chemical Engineering | |
curtin.accessStatus | Fulltext not available |
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