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dc.contributor.authorMoller, Kasper
dc.contributor.authorJørgensen, M.
dc.contributor.authorFogh, A.
dc.contributor.authorJensen, Torben
dc.identifier.citationMoller, K. and Jørgensen, M. and Fogh, A. and Jensen, T. 2017. Perovskite alkali metal samarium borohydrides: Crystal structures and thermal decomposition. Dalton Transactions. 46 (35): pp. 11905-11912.

© 2017 The Royal Society of Chemistry. A new synthesis method of samarium borohydride, Sm(BH4)2, using tetrahydrofuran borane, THF-BH3, and samarium hydride, SmH2, has been demonstrated and verified. The synthesised Sm(BH4)2was mechanochemically treated with MBH4, M = K, Rb, Cs. Initially, the formation of KSm(BH4)3is observed while subsequent heat treatment is necessary to form MSm(BH4)3, M = Rb, Cs. The new compounds crystallise in orthorhombic unit cells adopting perovskite-type 3D frameworks containing distorted [Sm(BH4)6] octahedra. In situ X-ray diffraction studies reveal two second-order polymorphic transitions of a-CsSm(BH4)3via a tetragonal intermediate, a'-CsSm(BH4)3, into a cubic high-temperature polymorph, ß-CsSm(BH4)3, resembling an ideal perovskite structure. The new compounds, MSm(BH4)3, are thermally stable up to T ~ 280 °C after which they decompose into mainly MBH4, SmH2and possibly SmB6and SmB12H12. Finally, after three cycles of hydrogen release and uptake, the storage capacity was 1.0 wt% for KSm(BH4)3and 0.84 wt% for RbSm(BH4)3and CsSm(BH4)3.

dc.publisherR S C Publications
dc.titlePerovskite alkali metal samarium borohydrides: Crystal structures and thermal decomposition
dc.typeJournal Article
dcterms.source.titleDalton Transactions
curtin.departmentSchool of Electrical Engineering, Computing and Mathematical Science (EECMS)
curtin.accessStatusFulltext not available

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