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dc.contributor.authorMocerino, Mauro
dc.contributor.authorOgden, Mark
dc.contributor.authorPettersen, Jade
dc.contributor.authorSkelton, B.
dc.contributor.authorWhite, A.
dc.date.accessioned2017-01-30T10:58:04Z
dc.date.available2017-01-30T10:58:04Z
dc.date.created2008-11-12T23:25:24Z
dc.date.issued2006
dc.identifier.citationMocerino, Mauro and Ogden, Mark and Pettersen, Jade and Skelton, Brian and White, Allan. 2006. One-pot Selective Formylation and Claisen Rearrangement on Calix[4]arenes. Supramolecular Chemistry 18 (2): 91-95.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/7153
dc.identifier.doi10.1080/10610270500419072
dc.description.abstract

A versatile synthon with formyl and allyl groups at the upper rim of calix[4]arene has been synthesized in two steps. Selective formylation of 25,27-diallyloxy-26,28-dihydroxycalix[4]arene, along with the Claisen rearrangement of the allyl groups, was achieved by reaction with hexamethylenetetraamine (hexamine) in glacial acetic acid. A control reaction of the dipropyl analogue shows that the selective formylation takes place independently of the Claisen rearrangement. The crystal structure of the dimethylacetal derivative of 5,17-diformyl-11,23-diallylcalix[4]arene is reported.

dc.publisherTaylor and Francis Ltd
dc.subjectClaisen rearrangement
dc.subjectCalixarenes
dc.subjectFormylation
dc.titleOne-pot Selective Formylation and Claisen Rearrangement on Calix[4]arenes
dc.typeJournal Article
dcterms.source.volume18
dcterms.source.number2
dcterms.source.monthapr
dcterms.source.startPage91
dcterms.source.endPage95
dcterms.source.titleSupramolecular Chemistry
curtin.note

This is an electronic version of an article published in Mocerino, Mauro and Ogden, Mark and Pettersen, Jade and Skelton, Brian and White, Allan (2006) One-pot Selective Formylation and Claisen Rearrangement on Calix[4]arenes, Supramolecular Chemistry 18(2):91-95, http://dx.doi.org/10.1080/10610270500419072

curtin.identifierEPR-838
curtin.accessStatusOpen access
curtin.facultyDepartment of Applied Chemistry
curtin.facultyDivision of Engineering, Science and Computing
curtin.facultyFaculty of Science


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