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    Enzyme-embedded metal-organic framework membranes on polymeric substrates for efficient CO2capture

    Access Status
    Fulltext not available
    Authors
    Zhang, Y.
    Wang, H.
    Liu, Jian
    Hou, J.
    Zhang, Y.
    Date
    2017
    Type
    Journal Article
    
    Metadata
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    Citation
    Zhang, Y. and Wang, H. and Liu, J. and Hou, J. and Zhang, Y. 2017. Enzyme-embedded metal-organic framework membranes on polymeric substrates for efficient CO2capture. Journal of Materials Chemistry A. 5 (37): pp. 19954-19962.
    Source Title
    Journal of Materials Chemistry A
    DOI
    10.1039/c7ta03719h
    ISSN
    2050-7488
    School
    WASM: Minerals, Energy and Chemical Engineering (WASM-MECE)
    URI
    http://hdl.handle.net/20.500.11937/71704
    Collection
    • Curtin Research Publications
    Abstract

    © 2017 The Royal Society of Chemistry. In this work, carbonic anhydrase (CA) molecules were embedded into metal-organic frameworks (MOFs) via physical absorption and chemical bonds, which could overcome the enzymatic inactivation and the poor separation property of pristine MOF materials. And then, these nanocomposites (enzyme-embedded MOFs) as the crystal seeds were in situ grown on oriented halloysite nanotube layers to develop novel biocatalytic composite membranes. These membranes exhibited optimal separation performance with a CO2/N2selectivity of 165.5, about 20.9 fold higher than that of the membrane without embedded CA molecules, surpassing the Robeson upper bound (2008). At the same time, the CO2permeance increased about 3.2 fold (from 7.6 GPU to 24.16 GPU). Importantly, the biocatalytic composite membranes showed good stability and mechanical properties and were easily scalable, which could be extended to industrial applications.

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