Chiral Metal–Organic Framework Hollow Nanospheres for High-Efficiency Enantiomer Separation

Wang, X.; Zhu, Y.; Liu, Jian; Liu, C.; Cao, C.; Song, W.

doi:10.1002/asia.201800330

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Authors

Wang, X.

Zhu, Y.

Liu, Jian

Liu, C.

Cao, C.

Song, W.

Date

2018

Type

Journal Article

Metadata

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Citation

Wang, X. and Zhu, Y. and Liu, J. and Liu, C. and Cao, C. and Song, W. 2018. Chiral Metal–Organic Framework Hollow Nanospheres for High-Efficiency Enantiomer Separation. Chemistry - An Asian Journal. 13 (12): pp. 1535-1538.

Source Title

Chemistry - An Asian Journal

DOI

10.1002/asia.201800330

ISSN

1861-4728

School

WASM: Minerals, Energy and Chemical Engineering (WASM-MECE)

URI

http://hdl.handle.net/20.500.11937/72311

Collection

Curtin Research Publications

Abstract

© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Chiral ZIF-8 hollow nanospheres with d-histidine as part of chiral ligands (denoted as H-d-his-ZIF-8) were prepared for separation of (±)-amine acids. Compared to bulk d-his-ZIF-8 without a hollow cavity, the prepared H-d-his-ZIF-8 showed 15 times higher separation capacity and higher ee values of 90.5 % for alanine, 95.2 % for glutamic acid and 92.6 % for lysine, respectively.