Chiral Metal–Organic Framework Hollow Nanospheres for High-Efficiency Enantiomer Separation
Fulltext not available
MetadataShow full item record
Wang, X. and Zhu, Y. and Liu, J. and Liu, C. and Cao, C. and Song, W. 2018. Chiral Metal–Organic Framework Hollow Nanospheres for High-Efficiency Enantiomer Separation. Chemistry - An Asian Journal. 13 (12): pp. 1535-1538.
Chemistry - An Asian Journal
WASM: Minerals, Energy and Chemical Engineering (WASM-MECE)
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Chiral ZIF-8 hollow nanospheres with d-histidine as part of chiral ligands (denoted as H-d-his-ZIF-8) were prepared for separation of (±)-amine acids. Compared to bulk d-his-ZIF-8 without a hollow cavity, the prepared H-d-his-ZIF-8 showed 15 times higher separation capacity and higher ee values of 90.5 % for alanine, 95.2 % for glutamic acid and 92.6 % for lysine, respectively.