The effect of pyridine modification of Ni-DOBDC on CO2 capture under humid conditions
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Authors
Bae, Y.
Liu, Jian
Wilmer, C.
Sun, H.
Dickey, A.
Kim, M.
Benin, A.
Willis, R.
Barpaga, D.
LeVan, M.
Snurr, R.
Date
2014Type
Journal Article
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Bae, Y. and Liu, J. and Wilmer, C. and Sun, H. and Dickey, A. and Kim, M. and Benin, A. et al. 2014. The effect of pyridine modification of Ni-DOBDC on CO2 capture under humid conditions. ChemComm. 50 (25): pp. 3296-3298.
Source Title
ChemComm
ISSN
School
WASM: Minerals, Energy and Chemical Engineering (WASM-MECE)
Collection
Abstract
The metal-organic framework Ni-DOBDC was modified with pyridine molecules to make the normally hydrophilic internal surface more hydrophobic. Experiments and molecular simulations show that the pyridine modification reduces H 2O adsorption while retaining substantial CO2 capacity under the conditions of interest for carbon capture from flue gas. © The Royal Society of Chemistry 2014.