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dc.contributor.authorAbad Galán, L.
dc.contributor.authorSobolev, A.
dc.contributor.authorSkelton, B.
dc.contributor.authorZysman-Colman, E.
dc.contributor.authorOgden, Mark
dc.contributor.authorMassi, Massimiliano
dc.identifier.citationAbad Galán, L. and Sobolev, A. and Skelton, B. and Zysman-Colman, E. and Ogden, M. and Massi, M. 2018. Energy transfer between Eu3+ and Nd3+ in near-infrared emitting β-triketonate coordination polymers. Dalton Transactions. 47 (35): pp. 12345-12352.

© The Royal Society of Chemistry. Isomorphous ß-triketonate-based lanthanoid polymers containing tris(4-methylbenzoyl)methanide (mtbm) and Rb+ with formula {[Ln(Rb)(mtbm)4]2}n (Ln = Eu3+ and Nd3+) have been synthesised and structurally characterised. The photophysical properties for the Nd3+ complex presented relatively long lifetimes and high quantum yields in comparison with analogous ß-diketonate complexes. Mixed lanthanoid complexes were also formed and their luminescence properties studied, with effective sensitisation of the 4F3/2 of Nd3+via the 5D0 of Eu3+, which is to the best of our knowledge the first example of Eu3+ to Nd3+ sensitisation in a structurally defined coordination complex or polymer.

dc.publisherR S C Publications
dc.titleEnergy transfer between Eu3+ and Nd3+ in near-infrared emitting β-triketonate coordination polymers
dc.typeJournal Article
dcterms.source.titleDalton Transactions
curtin.departmentSchool of Molecular and Life Sciences (MLS)
curtin.accessStatusFulltext not available

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