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    Hybrid C<inf>3</inf>N<inf>4</inf>/Fluorine-Doped Tin Oxide Electrode Transfers Hydride for 1,4-NADH Cofactor Regeneration

    Access Status
    Fulltext not available
    Authors
    Cazelles, R.
    Liu, Jian
    Antonietti, M.
    Date
    2015
    Type
    Journal Article
    
    Metadata
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    Citation
    Cazelles, R. and Liu, J. and Antonietti, M. 2015. Hybrid C<inf>3</inf>N<inf>4</inf>/Fluorine-Doped Tin Oxide Electrode Transfers Hydride for 1,4-NADH Cofactor Regeneration. ChemElectroChem. 2 (3): pp. 333-337.
    Source Title
    ChemElectroChem
    DOI
    10.1002/celc.201402421
    ISSN
    2196-0216
    School
    WASM: Minerals, Energy and Chemical Engineering (WASM-MECE)
    URI
    http://hdl.handle.net/20.500.11937/73286
    Collection
    • Curtin Research Publications
    Abstract

    © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Herein, we report the use of graphitic carbon nitride (C&lt;inf&gt;3&lt;/inf&gt;N&lt;inf&gt;4&lt;/inf&gt;)-modified fluorine-doped tin oxide electrodes for the electroregeneration of reduced nicotinamide adenine dinucleotide phosphate (NADH). We synthesized and functionalized these hybrid electrodes by using anodic aluminum-oxide-templated C&lt;inf&gt;3&lt;/inf&gt;N&lt;inf&gt;4&lt;/inf&gt; growth. Electrochemical activation of the semiconducting C&lt;inf&gt;3&lt;/inf&gt;N&lt;inf&gt;4&lt;/inf&gt; islands with a rhodium complex permits selective regeneration of biologically active 1,4-NADH cofactor. A ride for the hydride: Graphitic carbon nitride (C&lt;inf&gt;3&lt;/inf&gt;N&lt;inf&gt;4&lt;/inf&gt;)-modified fluorine-doped tin oxide (FTO) electrodes are used for the electroregeneration of reduced nicotinamide adenine dinucleotide phosphate (NADH). These hybrid electrodes are synthesized by using anodic aluminum-oxide-templated C&lt;inf&gt;3&lt;/inf&gt;N&lt;inf&gt;4&lt;/inf&gt; growth. Electrochemical activation of the semiconducting C&lt;inf&gt;3&lt;/inf&gt;N&lt;inf&gt;4&lt;/inf&gt; islands with a rhodium complex permits selective regeneration of biologically active 1,4-NADH cofactor.

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