Show simple item record

dc.contributor.authorLiu, C.
dc.contributor.authorLiu, Jian
dc.contributor.authorYang, S.
dc.contributor.authorCao, C.
dc.contributor.authorSong, W.
dc.date.accessioned2018-12-13T09:16:40Z
dc.date.available2018-12-13T09:16:40Z
dc.date.created2018-12-12T02:46:48Z
dc.date.issued2016
dc.identifier.citationLiu, C. and Liu, J. and Yang, S. and Cao, C. and Song, W. 2016. Palladium Nanoparticles Encapsulated in a Silicalite-1 Zeolite Shell for Size-Selective Catalysis in Liquid-Phase Solution. ChemCatChem. 8 (7): pp. 1279-1282.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/73485
dc.identifier.doi10.1002/cctc.201501383
dc.description.abstract

© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Size-selective catalysis is of great significance in both fundamental research and industrial applications. One well-known example is zeolite-based catalysts, which show remarkable size selectivity in gas-phase reactions. However, very few of these catalysts are realized in liquid-phase solution. Herein, we report an efficient route to produce a composite composed of Pd nanoparticles encapsulated in a silicalite-1 zeolite shell. This composite shows sharp size-selective catalysis in the hydrogenation of olefin aldehydes in aqueous solution. Owing to the pore-size limitation of the silicalite-1 zeolite shell (0.53×0.56 nm), the catalyst shows high activity in the hydrogenation of 3-methyl-2-butenal (0.38×0.62 nm) and cinnamaldehyde (0.54×0.92 nm) but no activity for the hydrogenation of 3,3-diphenylacrylaldehyde (0.81×1.0 nm). A catalyst with this type of structure can be applied to load other metal nanoparticles and can serve as a useful platform to study heterogeneous size-selective catalysis in liquid solution.

dc.publisherWILEY-V C H VERLAG GMBH,
dc.titlePalladium Nanoparticles Encapsulated in a Silicalite-1 Zeolite Shell for Size-Selective Catalysis in Liquid-Phase Solution
dc.typeJournal Article
dcterms.source.volume8
dcterms.source.number7
dcterms.source.startPage1279
dcterms.source.endPage1282
dcterms.source.issn1867-3880
dcterms.source.titleChemCatChem
curtin.departmentWASM: Minerals, Energy and Chemical Engineering (WASM-MECE)
curtin.accessStatusFulltext not available


Files in this item

FilesSizeFormatView

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record