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dc.contributor.authorBadban, S.
dc.contributor.authorHyde, A.
dc.contributor.authorPhan, Chi
dc.date.accessioned2019-02-19T04:16:16Z
dc.date.available2019-02-19T04:16:16Z
dc.date.created2019-02-19T03:58:25Z
dc.date.issued2017
dc.identifier.citationBadban, S. and Hyde, A. and Phan, C. 2017. Hydrophilicity of Nonanoic Acid and Its Conjugate Base at the Air/Water Interface. ACS Omega. 2 (9): pp. 5565-5573.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/74226
dc.identifier.doi10.1021/acsomega.7b00960
dc.description.abstract

A general adsorption model based on partial dissociation was developed for carboxylic acids. The model was applied to the adsorption of nonanoic acid at the air/water interface. Two cases were selected for experimental verification: acid-only and acid with a constant Na+OH– concentration. The model was applied simultaneously at both conditions, and the hydrophilicity of the ionic states was quantified by the adsorption constants, KA and KAH. It was found that the adsorption constant for the acidic group is significantly higher than that for the carboxylate group, KAH/KA ∼ 272. The model lays important groundwork for modeling and predicting carboxylic/carboxylate adsorption.

dc.titleHydrophilicity of Nonanoic Acid and Its Conjugate Base at the Air/Water Interface
dc.typeJournal Article
dcterms.source.volume2
dcterms.source.number9
dcterms.source.startPage5565
dcterms.source.endPage5573
dcterms.source.issn2470-1343
dcterms.source.titleACS Omega
curtin.departmentWASM: Minerals, Energy and Chemical Engineering (WASM-MECE)
curtin.accessStatusFulltext not available


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