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dc.contributor.authorJones, Franca
dc.contributor.authorOgden, Mark
dc.contributor.authorRadomirovic, T.
dc.date.accessioned2019-02-19T04:17:42Z
dc.date.available2019-02-19T04:17:42Z
dc.date.created2019-02-19T03:58:29Z
dc.date.issued2019
dc.identifier.citationJones, F. and Ogden, M. and Radomirovic, T. 2019. The impact of sulfite ions on barium sulfate crystallization. Journal of Crystal Growth. 507: pp. 213-219.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/74675
dc.identifier.doi10.1016/j.jcrysgro.2018.11.022
dc.description.abstract

© 2018 Elsevier B.V. In this manuscript we investigate an inorganic, anionic promoter of barium sulfate crystallization. Sulfite ions are found to promote barium sulfate crystallization at low concentrations. Turbidimetric experiments show homogenous nucleation promotion and AFM results show possible 2D nucleation promotion in the presence of sulfite ions. Growth promotion appears to be mainly in the c-axis relative to the other faces according to morphology results at low S values. Analysis of the sulfite ion impact by assuming it completely oxidizes to sulfate did not adequately explain all experimental results, suggesting that these ions also interact in some other way. One mechanism by which sulfite might promote barium sulfate crystallization is by promoting de-solvation of the barium ion by weakly complexing with it.

dc.publisherElsevier
dc.titleThe impact of sulfite ions on barium sulfate crystallization
dc.typeJournal Article
dcterms.source.volume507
dcterms.source.startPage213
dcterms.source.endPage219
dcterms.source.issn0022-0248
dcterms.source.titleJournal of Crystal Growth
curtin.departmentSchool of Molecular and Life Sciences (MLS)
curtin.accessStatusFulltext not available


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