View Item 

Metal coordination with an amide-functionalized axially chiral resorcinarene

Access Status
Open access
Authors
Vaughan, Jamila
Bertata, Munna Ali Mohamed
Skelton, B.W.
Ogden, Mark
Mocerino, Mauro
Date
2019
Type
Journal Article

Metadata
Show full item record
Citation
Vaughan, J. and Bertata, M.A.M. and Skelton, B.W. and Ogden, M.I. and Mocerino, M. 2019. Metal coordination with an amide-functionalized axially chiral resorcinarene. Journal of Inclusion Phenomena and Macrocyclic Chemistry. 94 (3-4): pp. 229-239.
Source Title
Journal of Inclusion Phenomena and Macrocyclic Chemistry
DOI
ISSN
Faculty
Faculty of Science and Engineering
School
School of Molecular and Life Sciences (MLS)
Remarks

The final publication is available at Springer via http://dx.doi.org/10.1007/s10847-019-00922-w

URI
Collection
Abstract

The synthesis and characterization of an amide-functionalized axially chiral resorcinarene, 14,36,56,76-tetra-2-oxo-2-(2-hydroxyethylamino)ethoxy-16,34,54,74-tetramethoxy-2,4,6,8- tetrapropylresorcin[4]arene, is reported. Metal complexation with picrate salts gave crystalline products that could be structurally characterised for calcium, lanthanum, praseodymium, and ytterbium. While the details of these structures vary, the metal–ligand interactions are remarkably consistent, with coordination polymers formed through interaction between three of the amide O atoms, each binding to a different metal atom. No other potential donor atom of the macrocycle is bound to the metal atoms, with the coordination spheres completed by solvent or picrate donor O atoms.