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dc.contributor.authorNguyen, C.V.
dc.contributor.authorNakahara, H.
dc.contributor.authorShibata, O.
dc.contributor.authorPhan, Chi
dc.date.accessioned2020-05-14T05:07:13Z
dc.date.available2020-05-14T05:07:13Z
dc.date.issued2020
dc.identifier.citationNguyen, C.V. and Nakahara, H. and Shibata, O. and Phan, C.M. 2020. Adsorption of sodium iodine at air/water interface. Journal of Molecular Liquids. 298: Article No. 112076.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/79138
dc.identifier.doi10.1016/j.molliq.2019.112076
dc.description.abstract

© 2019 Elsevier B.V.

The change in surface potential was measured for NaI solutions. The modelled surface charge was then calculated and compared with molecular simulations. It was found that I− was enhanced at the air/water interface more than Na+. The result, which was confirmed by simulations, was opposite to the previous observation with NaCl. The trend is also consistent with anionic effects: larger and more polar anions adsorbed stronger at the air/water interface. The theoretical model was applied successfully to describe the changes for both systems, which are positive for NaCl and negative for NaI, respectively. The combined results of the two systems also revealed that the self-ionization of pure water induced a positive surface charge at 16.9 mV.

dc.languageEnglish
dc.publisherELSEVIER
dc.subjectScience & Technology
dc.subjectPhysical Sciences
dc.subjectChemistry, Physical
dc.subjectPhysics, Atomic, Molecular & Chemical
dc.subjectChemistry
dc.subjectPhysics
dc.subjectSodium iodine
dc.subjectSurface potential
dc.subjectSurface charge
dc.subjectVIBRATIONAL SPECTROSCOPY
dc.subjectMOLECULAR-STRUCTURE
dc.subjectLIQUID INTERFACES
dc.subjectFORCE-FIELD
dc.subjectSURFACE
dc.subjectWATER
dc.subjectDYNAMICS
dc.subjectIONS
dc.titleAdsorption of sodium iodine at air/water interface
dc.typeJournal Article
dcterms.source.volume298
dcterms.source.issn0167-7322
dcterms.source.titleJournal of Molecular Liquids
dc.date.updated2020-05-14T05:07:13Z
curtin.departmentWASM: Minerals, Energy and Chemical Engineering
curtin.accessStatusFulltext not available
curtin.facultyFaculty of Science and Engineering
curtin.contributor.orcidPhan, Chi [0000-0002-1565-8193]
curtin.contributor.orcidNguyen, Van Cuong [0000-0003-0307-2969]
curtin.contributor.researcheridPhan, Chi [P-3775-2015]
curtin.identifier.article-numberARTN 112076
dcterms.source.eissn1873-3166
curtin.contributor.scopusauthoridPhan, Chi [7004175765]
curtin.contributor.scopusauthoridNguyen, Van Cuong [56843313800]
dc.date.embargoEnd2021-11-07


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