Partial functionalisation of C4-symmetric tetramethoxyresorcinarenes
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This is an accepted manuscript of an article published by Taylor & Francis in Supramolecular Chemistry on 30/05/2019 available online at http://www.tandfonline.com/10.1080/10610278.2019.1620949.
© 2019 Informa UK Limited, trading as Taylor & Francis Group. Investigations into the distal-functionalisation of the phenols of racemic C4-symmetric tetramethoxyresorcinarene has led to a simple, single-step procedure that allows the isolation of gram quantities of partially silylated derivatives, with the targeted distally silylated resorcinarene being obtained in a yield of 31%. These partially silylated derivatives would serve as versatile intermediates for the selective functionalisation of this elegant architecture. The solid-state structures of many of these derivatives have been determined by single crystal X-ray crystallography.
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