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    Partial functionalisation of C4-symmetric tetramethoxyresorcinarenes

    80394.pdf (2.031Mb)
    Access Status
    Open access
    Authors
    Tan, Daniel
    Massera, C.
    Mocerino, Mauro
    Date
    2019
    Type
    Journal Article
    
    Metadata
    Show full item record
    Citation
    Tan, D.A. and Massera, C. and Mocerino, M. 2019. Partial functionalisation of C4-symmetric tetramethoxyresorcinarenes. Supramolecular Chemistry. 31 (7): pp. 442-450.
    Source Title
    Supramolecular Chemistry
    DOI
    10.1080/10610278.2019.1620949
    ISSN
    1061-0278
    Faculty
    Faculty of Science and Engineering
    School
    School of Molecular and Life Sciences (MLS)
    Remarks

    This is an accepted manuscript of an article published by Taylor & Francis in Supramolecular Chemistry on 30/05/2019 available online at http://www.tandfonline.com/10.1080/10610278.2019.1620949.

    URI
    http://hdl.handle.net/20.500.11937/80332
    Collection
    • Curtin Research Publications
    Abstract

    © 2019 Informa UK Limited, trading as Taylor & Francis Group. Investigations into the distal-functionalisation of the phenols of racemic C4-symmetric tetramethoxyresorcinarene has led to a simple, single-step procedure that allows the isolation of gram quantities of partially silylated derivatives, with the targeted distally silylated resorcinarene being obtained in a yield of 31%. These partially silylated derivatives would serve as versatile intermediates for the selective functionalisation of this elegant architecture. The solid-state structures of many of these derivatives have been determined by single crystal X-ray crystallography.

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