Cation solvation in the solid state - temperature-dependent crystal structures in some metal perchlorates solvated by dimethylsulfoxide
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Problems arising from the extensive disorder characteristic of the crystalline lattice of dmso solvates of metal perchlorates at room temperature can in many cases be ameliorated or removed at "low" temperature. Present studies of several M(ClO4)n . 6dmso (n=2,3) species and Dy(ClO4)3 . 8dmso have allowed detailed definition of several homoleptic dmso-solvated metal cations, all of which contain dmso as an O-bound unidentate ligand and which appear to closely confirm the forms of solvated cations deduced from independent solution studies.
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Fillingham, Ryan; Boon, Matthew; Javaid, Shaghraf ; Saunders, J.Alex; Jones, Franca (2021)Crystallisation is performed in a non-aqueous solvent, dimethylsulfoxide (DMSO), in order to determine what the role of water is on the crystallisation pathway. In both water and DMSO environments the particles do not ...
Hughes, Zak; Mancera, Ricardo (2013)ell membrane phospholipid bilayers can be damaged by the large amounts of dimethyl sulphoxide (DMSO) commonly used in cryopreservation. The interaction of DMSO with model bilayers consisting of 1,2-dioleoyl-sn-glycero-3 ...
Hydrated Lanthanoid Complexes of 5-(2'-Pyridyl)tetrazole Formed in the Presence of Dimethyl SulfoxideD'Alessio, D.; Karagiannidis, L.; Skelton, B.; Massi, Massimiliano; Ogden, Mark (2012)Reaction of DMSO solvates of lanthanoid nitrates or perchlorates with 5-(2'-pyridyl)tetrazole (pytz) and triethylamine in organic solvents resulted in the unexpected crystallization of hydrates, rather than DMSO solvates. ...