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    Cation solvation in the solid state - temperature-dependent crystal structures in some metal perchlorates solvated by dimethylsulfoxide

    Access Status
    Fulltext not available
    Authors
    Chan, E.
    Cox, B.
    Harrowfield, J.
    Ogden, Mark
    Skelton, B.
    White, A.
    Date
    2004
    Type
    Journal Article
    
    Metadata
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    Citation
    Chan, Eric and Cox, Brian and Harrowfield, Jack and Ogden, Mark and Skelton, Brian and White, Allan. 2004. Cation solvation in the solid state - temperature-dependent crystal structures in some metal perchlorates solvated by dimethylsulfoxide. Inorganica Chimica Acta 357 (8): 2365-2373.
    Source Title
    Inorganica Chimica Acta
    DOI
    10.1016/j.ica.2003.12.035
    Faculty
    Department of Applied Chemistry
    Division of Engineering, Science and Computing
    Faculty of Science
    URI
    http://hdl.handle.net/20.500.11937/8074
    Collection
    • Curtin Research Publications
    Abstract

    Problems arising from the extensive disorder characteristic of the crystalline lattice of dmso solvates of metal perchlorates at room temperature can in many cases be ameliorated or removed at "low" temperature. Present studies of several M(ClO4)n . 6dmso (n=2,3) species and Dy(ClO4)3 . 8dmso have allowed detailed definition of several homoleptic dmso-solvated metal cations, all of which contain dmso as an O-bound unidentate ligand and which appear to closely confirm the forms of solvated cations deduced from independent solution studies.

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