Cation solvation in the solid state - temperature-dependent crystal structures in some metal perchlorates solvated by dimethylsulfoxide
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Problems arising from the extensive disorder characteristic of the crystalline lattice of dmso solvates of metal perchlorates at room temperature can in many cases be ameliorated or removed at "low" temperature. Present studies of several M(ClO4)n . 6dmso (n=2,3) species and Dy(ClO4)3 . 8dmso have allowed detailed definition of several homoleptic dmso-solvated metal cations, all of which contain dmso as an O-bound unidentate ligand and which appear to closely confirm the forms of solvated cations deduced from independent solution studies.
Chan, Eric and Cox, Brian and Harrowfield, Jack and Ogden, Mark and Skelton, Brian and White, Allan (2004) Cation solvation in the solid state - temperature-dependent crystal structures in some metal perchlorates solvated by dimethylsulfoxide, Inorganica Chimica Acta 357(8):2365-2373.
The link to this article is: http://dx.doi.org/10.1016/j.ica.2003.12.035
Copyright 2004 Elsevier B.V. All rights reserved.
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