Physicochemical Characterization of a Na-H-F Thermal Battery Material
dc.contributor.author | Humphries, Terry | |
dc.contributor.author | Rawal, A. | |
dc.contributor.author | Rowles, Matthew | |
dc.contributor.author | Prause, C.R. | |
dc.contributor.author | Bird, Julianne | |
dc.contributor.author | Paskevicius, Mark | |
dc.contributor.author | Sofianos, M. Veronica | |
dc.contributor.author | Buckley, Craig | |
dc.date.accessioned | 2021-01-05T07:41:39Z | |
dc.date.available | 2021-01-05T07:41:39Z | |
dc.date.issued | 2020 | |
dc.identifier.citation | Humphries, T.D. and Rawal, A. and Rowles, M.R. and Prause, C.R. and Bird, J.E. and Paskevicius, M. and Sofianos, M.V. et al. 2020. Physicochemical Characterization of a Na-H-F Thermal Battery Material. Journal of Physical Chemistry C. 124 (9): pp. 5053-5060. | |
dc.identifier.uri | http://hdl.handle.net/20.500.11937/82255 | |
dc.identifier.doi | 10.1021/acs.jpcc.9b10934 | |
dc.description.abstract |
Copyright © 2020 American Chemical Society. Fluorine-substituted sodium hydride is investigated for application as a thermal energy storage material inside thermal batteries. A range of compositions of NaHxF1-x (x = 0, 0.5, 0.7, 0.85, 0.95, 1) have been studied using synchrotron radiation powder X-ray diffraction (SR-XRD), near-edge X-ray absorption fine structure spectroscopy (NEXAFS), and nuclear magnetic resonance spectroscopy (NMR), with the thermal conductivity and melting points also being determined. SR-XRD and NMR spectroscopy studies identified that the solid solutions formed during synthesis contain multiple phases rather than a single stoichiometric compound, despite the materials exhibiting a single melting point. As the fluorine content of the materials increases, the Na-H(F) bond length decreases, increasing the stability of the compound. This trend is also observed during melting point analysis where increasing the fluorine content increases the melting point of the material; that is, x < 0.3 (i.e., F- > 0.7) enables melting at temperatures above 750 °C. | |
dc.language | English | |
dc.publisher | AMER CHEMICAL SOC | |
dc.relation.sponsoredby | http://purl.org/au-research/grants/arc/LP120101848 | |
dc.relation.sponsoredby | http://purl.org/au-research/grants/arc/LP150100730 | |
dc.relation.sponsoredby | http://purl.org/au-research/grants/arc/FT160100303 | |
dc.subject | Science & Technology | |
dc.subject | Physical Sciences | |
dc.subject | Technology | |
dc.subject | Chemistry, Physical | |
dc.subject | Nanoscience & Nanotechnology | |
dc.subject | Materials Science, Multidisciplinary | |
dc.subject | Chemistry | |
dc.subject | Science & Technology - Other Topics | |
dc.subject | Materials Science | |
dc.subject | THERMOCHEMICAL ENERGY-STORAGE | |
dc.subject | SODIUM | |
dc.subject | HYDRIDE | |
dc.subject | THERMODYNAMICS | |
dc.subject | OPTIMIZATION | |
dc.subject | SPECTRA | |
dc.title | Physicochemical Characterization of a Na-H-F Thermal Battery Material | |
dc.type | Journal Article | |
dcterms.source.volume | 124 | |
dcterms.source.number | 9 | |
dcterms.source.startPage | 5053 | |
dcterms.source.endPage | 5060 | |
dcterms.source.issn | 1932-7447 | |
dcterms.source.title | Journal of Physical Chemistry C | |
dc.date.updated | 2021-01-05T07:41:38Z | |
curtin.note |
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Physicochemical Characterization of a Na-H-F Thermal Battery Material, copyright © American Chemical Society, after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.jpcc.9b10934 | |
curtin.department | John de Laeter Centre (JdLC) | |
curtin.department | School of Electrical Engineering, Computing and Mathematical Sciences (EECMS) | |
curtin.accessStatus | Open access | |
curtin.faculty | Faculty of Science and Engineering | |
curtin.contributor.orcid | Rowles, Matthew [0000-0002-7448-6774] | |
curtin.contributor.orcid | Humphries, Terry [0000-0003-1015-4495] | |
curtin.contributor.orcid | Paskevicius, Mark [0000-0003-2677-3434] | |
curtin.contributor.orcid | Buckley, Craig [0000-0002-3075-1863] | |
curtin.contributor.orcid | Bird, Julianne [0000-0002-0411-5361] | |
curtin.contributor.orcid | Sofianos, M. Veronica [0000-0002-9654-1463] | |
curtin.contributor.researcherid | Paskevicius, Mark [K-1638-2013] | |
curtin.contributor.researcherid | Buckley, Craig [B-6753-2013] | |
dcterms.source.eissn | 1932-7455 | |
curtin.contributor.scopusauthorid | Rowles, Matthew [24476696900] | |
curtin.contributor.scopusauthorid | Humphries, Terry [12798136600] | |
curtin.contributor.scopusauthorid | Paskevicius, Mark [23025599100] | |
curtin.contributor.scopusauthorid | Buckley, Craig [56412440100] [7202815196] |