Palladium, rhodium and platinum complexes of ortho-xylyl-linked bis-N-heterocyclic carbenes: Synthesis, structure and catalytic activity
MetadataShow full item record
New Pd(II), Pt(II) and Rh(I) N-heterocyclic carbene (NHC) complexes containing two NHC units linked by an ortho-xylyl group are described and structurally and spectroscopically characterised. The Pt(II) complexes represent the first examples of Pt-bis(NHC) complexes where the NHC units are linked by an ortho-xylyl group. Functionalisation of the bis(NHC) ligands with heptyl groups has been used as a means of enhancing the solubility of the complexes, in order to facilitate spectroscopic characterisation and catalytic studies. The catalytic activity of the palladium(II) complexes in Heck and Suzuki cross-coupling reactions has been examined to investigate any effects of the diverse structural changes, though these appear to be insignificant.
Showing items related by title, author, creator and subject.
Complex Adaptive Systems and Conversation Analysis: A New Perspective for Consumer Behaviour Research?Whiteley, Jervis (2002)The research question for this study is “Can concepts from complex adaptive systems and conversation analysis be used to research consumer behaviour?" This is, primarily, a theoretical question. After a wide-ranging ...
Ling, B.; Ho, C.; Wang, L.; Teo, Kok Lay; Tse, C.k; Dai, Q. (2014)Some of the nodes of complex social networks may support for a given proposal, while the rest of the nodes may be against the given proposal. Even though all the nodes support for or are against the given proposal, the ...
A primary study of the Jilin-Heilongjiang high-pressure metamorphic belt: Evidence and tectonic implicationsZhou, Jian-Bo; Han, J.; Wilde, Simon; Guo, X.; Zeng, W.; Cao, J. (2013)Jilin-Heilongjiang high-pressure metamorphic belt (Ji-Hei HP Belt), around western and southern margin of the Jiamusi-Khanka block, is the high-pressure metamorphic belt with the accretionary complex due to the subduction ...