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    ROMP (co)polymers with pendent alkyne side groups: post-polymerization modification employing thiol–yne and CuAAC coupling chemistries

    Access Status
    Fulltext not available
    Authors
    van Hensbergen, J.
    Burford, R.
    Lowe, Andrew
    Date
    2014
    Type
    Journal Article
    
    Metadata
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    Citation
    van Hensbergen, J. and Burford, R. and Lowe, A. 2014. ROMP (co)polymers with pendent alkyne side groups: post-polymerization modification employing thiol–yne and CuAAC coupling chemistries. Polymer Chemistry. 5 (18): pp. 5339-5349.
    Source Title
    Polymer Chemistry
    DOI
    10.1039/c4py00604f
    ISSN
    1759-9954
    URI
    http://hdl.handle.net/20.500.11937/8801
    Collection
    • Curtin Research Publications
    Abstract

    The synthesis of a series of copolymers via ring-opening metathesis polymerization (ROMP) containing pendent trimethylsilyl-protected alkyne functional groups is described. Deprotection of the protected ynes yields copolymers with free alkyne functionality that can be utilized as a reactive handle for thiol–yne (TYC) and Cu-catalyzed alkyne–azide coupling (CuAAC) either independently or together.

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