Investigation of the structure and magnetism in lanthanide ß-triketonate tetranuclear assemblies
| dc.contributor.author | Reid, Brodie | |
| dc.contributor.author | Woodward, R. | |
| dc.contributor.author | Fuller, Rebecca | |
| dc.contributor.author | Sobolev, A. | |
| dc.contributor.author | Skelton, B. | |
| dc.contributor.author | Ogden, Mark | |
| dc.contributor.author | Massi, Massimiliano | |
| dc.date.accessioned | 2017-01-30T11:09:40Z | |
| dc.date.available | 2017-01-30T11:09:40Z | |
| dc.date.created | 2016-05-29T19:30:35Z | |
| dc.date.issued | 2016 | |
| dc.identifier.citation | Reid, B. and Woodward, R. and Fuller, R. and Sobolev, A. and Skelton, B. and Ogden, M. and Massi, M. 2016. Investigation of the structure and magnetism in lanthanide ß-triketonate tetranuclear assemblies. Journal of Coordination Chemistry. 69 (11-13): pp. 1852-1863. | |
| dc.identifier.uri | http://hdl.handle.net/20.500.11937/8944 | |
| dc.identifier.doi | 10.1080/00958972.2016.1180375 | |
| dc.description.abstract |
The preparation of discrete tetranuclear lanthanide/alkali metal (Ae) assemblies bearing a tribenzoylmethane ligand (LH) is discussed. These assemblies have the general formula [Ln(Ae·HOEt)(L)4]2, where Ln3+ = Gd3+, Tb3+, Dy3+, Ho3+ and Ae+ = Na+, K+, Rb+. The coordination geometries of the lanthanide species were analyzed and compared, revealing a trend between an eight-coordinate square antiprism and triangular dodecahedron dependent on the nature of lanthanide, alkali metal, and lattice solvent. The potassium-containing analogs were also analyzed for their magnetic susceptibility. | |
| dc.publisher | Taylor & Francis | |
| dc.title | Investigation of the structure and magnetism in lanthanide ß-triketonate tetranuclear assemblies | |
| dc.type | Journal Article | |
| dcterms.source.startPage | 1 | |
| dcterms.source.endPage | 12 | |
| dcterms.source.issn | 0095-8972 | |
| dcterms.source.title | Journal of Coordination Chemistry | |
| curtin.department | Nanochemistry Research Institute | |
| curtin.accessStatus | Open access |