Polymorphism and its effects on the magnetic behaviour of the [Fe(sal2-trien)][Ni(dmit)2] spin-crossover complex
Citation
Faulmann, C. and Szilagyi, P. and Jacob, K. and Chahine, J. and Valade, L. 2009. Polymorphism and its effects on the magnetic behaviour of the [Fe(sal2-trien)][Ni(dmit)2] spin-crossover complex. New Journal of Chemistry. 33: pp. 1268-1276.
Source Title
New Journal of Chemistry
ISSN
Collection
Abstract
The syntheses, structural characterisation, and magnetic and spectroscopic properties of three new polymorphs of the spin-crossover complex [Fe(sal2-trien)][Ni(dmit)2] are reported. The results are discussed as a function of their intra- and intermolecular arrangement. Correlation of their crystal structures and magnetic properties suggest that some torsion angles play a significant role in the magnetic properties of this class of compounds. Intermolecular contacts are also of importance, and the nature of the short contacts between molecular species seems to be more crucial than their number in the allowance of spin-crossover.
Related items
Showing items related by title, author, creator and subject.
-
Lawrence, Shane Michael (2011)Multiferroic materials have recently begun to attract significant scientific interest due to their potential applications in the design of modern electronic devices. Currently, the magnetic properties of materials form ...
-
Tripathi, M.; Mujawar, Mubarak; Sahu, J.; Ganesan, P. (2017)© 2017 Scrivener Publishing LLC. Agricultural waste biomass is present in a large quantity in most of the countries have considered to be a suitable material for many applications because of their abundance, degradability ...
-
Li, Q.; Wolfs, Peter (2006)A zero-voltage switching (ZVS) two-inductor boost converter with an integrated magnetic structure has been previously proposed to achieve the size and cost reduction in the converter design with discrete magnetics. In the ...