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    Solubility of metal-boron-hydrogen compounds

    96769.pdf (1.687Mb)
    Access Status
    Open access
    Authors
    Nguyen, Thi Phuong Thao
    Humphries, Terry D.
    Hagemann, H.
    Buckley, Craig E.
    Jensen, T.R.
    Paskevicius, Mark
    Date
    2024
    Type
    Journal Article
    
    Metadata
    Show full item record
    Citation
    Nguyen, T.P.T. and Humphries, T.D. and Hagemann, H. and Buckley, C.E. and Jensen, T.R. and Paskevicius, M. 2024. Solubility of metal-boron-hydrogen compounds. Dalton Transactions. 54 (3): pp. 1199-1211.
    Source Title
    Dalton Transactions
    DOI
    10.1039/d4dt02256d
    ISSN
    1477-9226
    Faculty
    Faculty of Science and Engineering
    School
    School of Elec Eng, Comp and Math Sci (EECMS)
    Funding and Sponsorship
    http://purl.org/au-research/grants/arc/LP190100297
    http://purl.org/au-research/grants/arc/DP230100429
    http://purl.org/au-research/grants/arc/IC200100023
    URI
    http://hdl.handle.net/20.500.11937/97005
    Collection
    • Curtin Research Publications
    Abstract

    Boron-hydrogen compounds are of increasing importance as electrolytes in solid state batteries, for hydrogen storage and possibly as high temperature super conductors. Solvent based methods are of increasing importance to obtain pure products, for purification of materials and also for the synthesis of novel compounds. In this context, the solubility information of several classes of metal-boron-hydrogen compounds such as borohydrides, closo-decahydridodecaborates, closo-dodecahydridododecaborates, arachno- and nido-hydridoborates in typical solvents is vital. This information is currently dispersed in the literature, hence the need to present a cohesive summary and comparison of these properties. This review collects, analyses and discusses the available data to provide inspiration for the future design of new synthesis routes and the discovery of novel materials.

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