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dc.contributor.authorZhou, X.
dc.contributor.authorYuan, B.
dc.contributor.authorZhang, Lei
dc.contributor.authorHan, D.
dc.contributor.authorYou, T.
dc.date.accessioned2017-01-30T11:16:56Z
dc.date.available2017-01-30T11:16:56Z
dc.date.created2015-07-16T06:21:56Z
dc.date.issued2010
dc.identifier.citationZhou, X. and Yuan, B. and Zhang, L. and Han, D. and You, T. 2010. Determination of amino acids by Ru(bpy)32+ cathodic electrochemiluminescence with high sensitivity. Chemical Research in Chinese Universities. 26 (3): pp. 376-379.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/10129
dc.description.abstract

The unique cathodic electrochemiluminescence(ECL) emission of Ru(bpy)32+(bpy=2,2′-bipyridine) was observed via Nafion film at Au electrode[Au/Nafion/Ru(bpy)32+] at about 0.20 V(vs. Ag/AgCl) and applied to the determination of several amino acids without prior derivatization with high sensitivity. The cathodic electrochemiluminescence(ECL) exhibits the detection limits and linear ranges of several amino acids comparable to or better than those of capillary electrophoresis with conventional ECL detection method(at 1.10—1.20 V vs. Ag/AgCl) based on precolumn derivatization. The results suggest that the cathodic ECL is promising for the detection of amino acids in bioanalysis.

dc.publisherJilin Daxue
dc.relation.urihttps://www.google.com.au/?gws_rd=ssl#q=Determination+of+amino+acids+by+Ru%28bpy%2932%2B+cathodic+electrochemiluminescence+with+high+sensitivity
dc.subjectCathodic electrochemiluminescence
dc.subjectNafion
dc.subjectAu electrode
dc.subjectRu(bpy)/+
dc.titleDetermination of amino acids by Ru(bpy)32+ cathodic electrochemiluminescence with high sensitivity
dc.typeJournal Article
dcterms.source.volume26
dcterms.source.startPage376
dcterms.source.endPage379
dcterms.source.issn1005-9040
dcterms.source.titleChemical Research in Chinese Universities
curtin.accessStatusFulltext not available


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