Crystal structure and photoluminescence properties of Eu <sup>2+</sup>-activated Ba<inf>2</inf>LiB<inf>5</inf>O<inf>10</inf> phosphors
MetadataShow full item record
A novel orange-yellow-emitting Ba2LiB5O 10:Eu2+ phosphor has been synthesized by traditional high temperature solid state reaction. A monoclinic crystal structure of Barium lithiumborates Ba2LiB5O10 was verified by the investigation of X-ray diffraction (XRD). The compound crystallizes in the space group of P121/m1(11) (Z = 2) with the unit cell parameters a = 4.414(1) Å, b = 14.576(2) Å, c = 6.697(2) Å and ß = 104.26(2)°. Barium and lithium atoms are located in distorted octahedral and tetrahedral oxygen coordinations, respectively. Upon around 365 nm excitation, the Eu2+-activated Ba2LiB5O10 phosphors exhibit a single broad emission band with the maximum at about 587 nm, due to the 4f65d ? 4f7(8S7/2) transition of Eu2+. This work investigates the relationship between luminescence properties and structural characterization of the Ba2LiB 5O10: Eu2+. This newly developed phosphor shows high potential as a phosphor conversion for white LED applications. © 2011 Elsevier B.V. All rights reserved.
Showing items related by title, author, creator and subject.
Guo, M.; Huang, L.; Zhao, S.; Deng, D.; Wang, H.; Hua, Y.; Jia, Guohua; Xu, S. (2013)A series of phosphors with nominal compositions of Sr1.7M 0.3SiO4-xFx:0.01Eu2+, 0.08Mn 2+ (x=0, 0.01, 0.05, 0.1, 0.2) were synthesized through solid-state reaction technique. Their luminescent properties were studied. ...
Huang, L.; Guo, M.; Zhao, S.; Deng, D.; Wang, H.; Hua, Y.; Jia, Guohua; Xu, S. (2013)Ce3+, Tb3+ singly-doped and co-doped Ca 2LiSiO4F phosphors have been synthesized through conventional solid-state reaction. Their luminescence properties are studied. Under UV excitation, Ce3+ singly-doped Ca2LiSiO 4F ...
Enhanced red fluorescence in Sr 2Si 1-xGe xO 4:Eu 3+ phosphors by the substitution of Si by Ge for white light emitting diodesHuang, L.; Xu, S.; Guo, M.; Wang, C.; Hua, Y.; Zhao, S.; Deng, D.; Wang, H.; Jia, Guohua (2012)Eu 3-doped Sr 2Si 1-xGe xO 4 (x=0-1) phosphors have been prepared by the high temperature solid-state ...