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    Crystal structure and photoluminescence properties of Eu 2+-activated Ba2LiB5O10 phosphors

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    Fulltext not available
    Authors
    Wang, Q.
    Deng, D.
    Xu, S.
    Hua, Y.
    Huang, L.
    Wang, H.
    Zhao, S.
    Jia, Guohua
    Li, C.
    Date
    2011
    Type
    Journal Article
    
    Metadata
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    Citation
    Wang, Q. and Deng, D. and Xu, S. and Hua, Y. and Huang, L. and Wang, H. and Zhao, S. et al. 2011. Crystal structure and photoluminescence properties of Eu 2+-activated Ba2LiB5O10 phosphors. Optics Communications. 284 (22): pp. 5315-5318.
    Source Title
    Optics Communications
    DOI
    10.1016/j.optcom.2011.07.018
    ISSN
    0030-4018
    School
    Nanochemistry Research Institute
    URI
    http://hdl.handle.net/20.500.11937/10208
    Collection
    • Curtin Research Publications
    Abstract

    A novel orange-yellow-emitting Ba2LiB5O 10:Eu2+ phosphor has been synthesized by traditional high temperature solid state reaction. A monoclinic crystal structure of Barium lithiumborates Ba2LiB5O10 was verified by the investigation of X-ray diffraction (XRD). The compound crystallizes in the space group of P121/m1(11) (Z = 2) with the unit cell parameters a = 4.414(1) Å, b = 14.576(2) Å, c = 6.697(2) Å and ß = 104.26(2)°. Barium and lithium atoms are located in distorted octahedral and tetrahedral oxygen coordinations, respectively. Upon around 365 nm excitation, the Eu2+-activated Ba2LiB5O10 phosphors exhibit a single broad emission band with the maximum at about 587 nm, due to the 4f65d ? 4f7(8S7/2) transition of Eu2+. This work investigates the relationship between luminescence properties and structural characterization of the Ba2LiB 5O10: Eu2+. This newly developed phosphor shows high potential as a phosphor conversion for white LED applications. © 2011 Elsevier B.V. All rights reserved.

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